Solvent isotope effect and mechanism for the production of hydrogen and lactic acid from glycerol under hydrothermal alkaline conditions
文献情報
Min Zhang, Fangmin Jin
To discover the reaction mechanism for the production of hydrogen and lactic acid from glycerol under alkaline hydrothermal conditions, we identified the different intermediates involved during reactions by investigating the solvent isotope effect with 1H-NMR, 2H-NMR, LC-MS and Gas-MS analyses, and then proposed and proved a potential reaction mechanism.
関連文献
The role of reduction extent of graphene oxide in the photocatalytic performance of Ag/AgX (X = Cl, Br)/rGO composites and the pseudo-second-order kinetics reaction nature of the Ag/AgBr system
Weiyin Gao, Chenxin Ran, Minqiang Wang, Le Li, Zhongwang Sun, Xi Yao
DOI: 10.1039/C6CP03110B
Different routes to methanol: inelastic neutron scattering spectroscopy of adsorbates on supported copper catalysts
Timur Kandemir, Matthias Friedrich, Stewart F. Parker, Felix Studt, David Lennon, Robert Schlögl, Malte Behrens
DOI: 10.1039/C6CP00967K
Study of the reactivity of silica supported tantalum catalysts with oxygen followed by in situ HEROS
Wojciech Błachucki, Yves Kayser, Jean-Claude Dousse, Joanna Hoszowska, Daniel L. A. Fernandes
DOI: 10.1039/C5CP02950C
Super flexibility and stability of graphene nanoribbons under severe twist
Qiang Li, Qingzhong Xue, Chunyong Liang, Mingdong Dong
DOI: 10.1039/C6CP02580C
Revealing electronic structure changes in Chevrel phase cathodes upon Mg insertion using X-ray absorption spectroscopy
Liwen F. Wan, Joshua Wright, Brian R. Perdue, Timothy T. Fister, Soojeong Kim, Christopher A. Apblett, David Prendergast
DOI: 10.1039/C6CP02412B
Atomic elucidation of the cyclodextrin effects on DDT solubility and biodegradation
Mingzhen Zhang, Huipeng Gao, Jie Zheng, Lingyun Jia
DOI: 10.1039/C6CP02790C
Ultrafast and slow charge recombination dynamics of diketopyrrolopyrrole–NiO dye sensitized solar cells
Lei Zhang, Ludovic Favereau, Yoann Farré, Edgar Mijangos, Yann Pellegrin, Errol Blart, Fabrice Odobel, Leif Hammarström
DOI: 10.1039/C6CP01762B
Positional recurrence maps, a powerful tool to de-correlate static and dynamical disorder in distribution maps from molecular dynamics simulations: the case of Nd2NiO4+d
A. Piovano, A. Perrichon, M. Boehm, M. R. Johnson, W. Paulus
DOI: 10.1039/C5CP06464C
Spectacular enhancement of thermoelectric phenomena in chemically synthesized graphene nanoribbons with substitution atoms
K. Zberecki, R. Swirkowicz, M. Wierzbicki
DOI: 10.1039/C6CP02877B
こちらもおすすめ
5-苄基四氢吡咯并[3,4-c]吡咯-1,3[2H,3ah]-二酮の主な用途は何ですか?
5-苄基四氢吡咯并[3,4-c]吡咯-1,3[2H,3ah]-二酮は、主に薬理学的研究と合成化学に使用されます。また、特定の医薬品の合成原材料としても利用されま...
唾液酸路易ス Aを取り扱う際の実験室安全事項は何ですか?
唾液酸路易ス Aの取り扱いでは、個別の防護具(PPE)が必要で、手袋、顔面保護具、防塵マスクを着用します。ドラフトチャンバーを使用し、漏洩時の適切な処理を行うこ...
タルトブチル ((1-(2-クロロアセチル)ピペリジン-4-イルメチル)カーバamatはどの業界で使用されていますか?
タルトブチル ((1-(2-クロロアセチル)ピペリジン-4-イルメチル)カーバamatは、医薬品業界、ポリマー業界、センサー技術、半導体業界などで使用されていま...
3-烯丙基-2-羟基苯甲醛の物理化学的性質は何ですか?
3-烯丙基-2-羟基苯甲醛のCAS番号は24019-66-7です。物化性質としては、白色結晶性粉末で、分子量は174.22です。この化合物は水に溶けやすく、反応...
乳清酸 Potassium Orotateとは何ですか?
乳清酸 Potassium Orotateは、CAS番号24598-73-0の化合物で、乳清酸と Potassium(カリウム)による塩基です。化学式はC7H7...
4-甲基苯磺酸异丙酯はどの業界で使用されていますか?
4-甲基苯磺酸异丙酯は医薬品業界で広く使用されています。また、ポリマーの増塑剤や半導体製造におけるセンサー材料としても使用されることがあります。
6-(3- Florobenzen)-N-[1-(2,2,2- Trifluoroethyl)-4-Piperidinyl]-3-Pyridinycarboxamideはどの業界で使用されていますか?
6-(3-氟苯基)-N-[1-(2,2,2-三氟乙基)-4-哌啶基]-3-吡啶羧酰胺は医薬品産業で広く使用されており、その特性は抗炎症作用や抗ウイルス作用など、...
左西孟旦はどのように合成されますか?
左西孟旦は、3-[(2-メチルフェニル)-2-(4-メチルフェニル)-1-オキシエチル]-1,2,4-トリTürkiyeン-5-カルボン酸と4-メチルフェニル-...
3-乙氧基哌啶盐酸盐に適用される法規ガイドラインは何ですか?
CAS番号1159826-79-5の3-乙氧基哌啶盐酸盐は、GHS分類ではイエローカテゴリーに分類され、毒性物質として扱われます。REACH規則では、製造または...
Diethyl (hydroxymethyl)phosphonateの主な用途は何ですか?
Diethyl (hydroxymethyl)phosphonateは、医薬品の製造や農薬、合成化学の一部として利用されます。
掲載誌
Green Chemistry

Green Chemistry provides a unique forum for the publication of innovative research on the development of alternative green and sustainable technologies. The scope of Green Chemistry is based on, but not limited to, the definition proposed by Anastas and Warner (Green Chemistry: Theory and Practice, P T Anastas and J C Warner, Oxford University Press, Oxford, 1998). Green chemistry is the utilisation of a set of principles that reduces or eliminates the use or generation of hazardous substances in the design, manufacture and application of chemical products. Green Chemistry is at the frontiers of this continuously-evolving interdisciplinary science and publishes research that attempts to reduce the environmental impact of the chemical enterprise by developing a technology base that is inherently non-toxic to living things and the environment. Submissions on all aspects of research relating to the endeavour are welcome. The journal publishes original and significant cutting-edge research that is likely to be of wide general appeal. To be published, work must present a significant advance in green chemistry. Papers must contain a comparison with existing methods and demonstrate advantages over those methods before publication can be considered. For more information please see this Editorial. Coverage includes the following, but is not limited to: Design (e.g. biomimicry, design for degradation/recycling/reduced toxicity…) Reagents & Feedstocks (e.g. renewables, CO2, solvents, auxiliary agents, waste utilization…) Synthesis (e.g. organic, inorganic, synthetic biology…) Catalysis (e.g. homogeneous, heterogeneous, enzyme, whole cell…) Process (e.g. process design, intensification, separations, recycling, efficiency…) Energy (e.g. renewable energy, fuels, photovoltaics, fuel cells, energy storage, energy carriers…) Applications (e.g. electronics, dyes, consumer products, coatings, pharmaceuticals, preservatives, building materials, chemicals for industry/agriculture/mining…) Impact (e.g. safety, metrics, LCA, sustainability, (eco)toxicology…) Green chemistry is, by definition, a continuously-evolving frontier. Therefore, the inclusion of a particular material or technology does not, of itself, guarantee that a paper is suitable for the journal. To be suitable, the novel advance should have the potential for reduced environmental impact relative to the state of the art. Green Chemistry does not normally deal with research associated with 'end-of-pipe' or remediation issues.











![2-Methyl-2-propanyl 4-[3-(aminomethyl)phenyl]-1-piperazinecarboxylate structure 2-Methyl-2-propanyl 4-[3-(aminomethyl)phenyl]-1-piperazinecarboxylate structure](https://static.chemtradehub.com/structs/889/889948-55-4-5c12.webp)


