Incorporation of Mo and W into nanostructured BiVO4 films for efficient photoelectrochemical water oxidation
文献情報
Sean P. Berglund, Alexander J. E. Rettie, Son Hoang, C. Buddie Mullins
Porous, nanostructured BiVO4 films are incorporated with Mo and W by simultaneous evaporation of Bi, V, Mo, and W in vacuum followed by oxidation in air. Synthesis parameters such as the Bi : V : Mo : W atomic ratio and deposition angle are adjusted to optimize the films for photoelectrochemical (PEC) water oxidation. Films synthesized with a Bi : V : Mo : W atomic ratio of 46 : 46 : 6 : 2 (6% Mo, 2% W) demonstrate the best PEC performance with photocurrent densities 10 times higher than for pure BiVO4 and greater than previously reported for Mo and W containing BiVO4. The films consist of a directional, nanocolumnar layer beneath an irregular surface structure. Backside illumination utilizes light scattering off the irregular surface structure resulting in 30–45% higher photocurrent densities than for frontside illumination. To improve the kinetics for water oxidation Pt is photo-deposited onto the surface of the 6% Mo, 2% W BiVO4 films as an electrocatalyst. These films achieve quantum efficiencies of 37% at 1.1 V vs. RHE and 50% at 1.6 V vs. RHE for 450 nm light.
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Physical Chemistry Chemical Physics

Physical Chemistry Chemical Physics (PCCP) is an international journal co-owned by 19 physical chemistry and physics societies from around the world. This journal publishes original, cutting-edge research in physical chemistry, chemical physics and biophysical chemistry. To be suitable for publication in PCCP, articles must include significant innovation and/or insight into physical chemistry; this is the most important criterion that reviewers and Editors will judge against when evaluating submissions. The journal has a broad scope and welcomes contributions spanning experiment, theory, computation and data science. Topical coverage includes spectroscopy, dynamics, kinetics, statistical mechanics, thermodynamics, electrochemistry, catalysis, surface science, quantum mechanics, quantum computing and machine learning. Interdisciplinary research areas such as polymers and soft matter, materials, nanoscience, energy, surfaces/interfaces, and biophysical chemistry are welcomed if they demonstrate significant innovation and/or insight into physical chemistry. Joined experimental/theoretical studies are particularly appreciated when complementary and based on up-to-date approaches.














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