Thermodynamics of exciton/polaritons in one and two dimensional organic single-crystal microcavities
文献情報
Eric R. Bittner, Svitlana Zaster, Carlos Silva
We consider here the thermodynamics and phase-diagram of exciton/polaritons formed in low-dimensional organic single-crystal microcavities. Using the Dicke model for a lattice of Frenkel excitons coupled to a common cavity mode, we explore the transition between normal and condensate regimes as depending upon the exciton band-width and temperature of the polariton gas. We show that for one-dimensional conjugated polymers, the coexistence curve at low temperatures shifts towards lower critical coupling strengths as the exciton band-width is increased. We also consider the effect of orientational disorder in a two-dimensional polyacene slab on the formation of the polariton BEC. Our results indicate that while a small degree of orientational disorder will not have a profound effect on the critical exciton/photon coupling strength needed to produce the transition from normal to BEC regimes, BEC will likely be suppressed in glassy or strongly disordered molecular films.
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Physical Chemistry Chemical Physics (PCCP) is an international journal co-owned by 19 physical chemistry and physics societies from around the world. This journal publishes original, cutting-edge research in physical chemistry, chemical physics and biophysical chemistry. To be suitable for publication in PCCP, articles must include significant innovation and/or insight into physical chemistry; this is the most important criterion that reviewers and Editors will judge against when evaluating submissions. The journal has a broad scope and welcomes contributions spanning experiment, theory, computation and data science. Topical coverage includes spectroscopy, dynamics, kinetics, statistical mechanics, thermodynamics, electrochemistry, catalysis, surface science, quantum mechanics, quantum computing and machine learning. Interdisciplinary research areas such as polymers and soft matter, materials, nanoscience, energy, surfaces/interfaces, and biophysical chemistry are welcomed if they demonstrate significant innovation and/or insight into physical chemistry. Joined experimental/theoretical studies are particularly appreciated when complementary and based on up-to-date approaches.












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