Catalytic chain transfer and its derived macromonomers

文献情報

出版日 2011-07-26

DOI 10.1039/C1PY00224D

インパクトファクター 5.582

著者

Johan P. A. Heuts, Niels M. B. Smeets

原文を見る

要旨

An overview is given of cobalt-catalyzed chain transfer in free-radical polymerization and the chemistry and applications of its derived macromonomers. Catalytic chain transfer polymerization is a very efficient and versatile technique for the synthesis of functional macromonomers. Firstly the mechanism and kinetic aspects of the process are briefly discussed in solution/bulk and in emulsion polymerization, followed by a description of its application to produce functional macromonomers. The second part of this review briefly describes the behavior of the macromonomers as chain transfer agents and/or comonomers in second-stage radical polymerizations yielding polymers of more complex architectures. The review ends with a brief overview of post-polymerization modifications of the vinyl endfunctionality of the macromonomers yielding functional polymers with applications ranging from initiators in anionic polymerization to end-functional lectin-binding glycopolymers.

掲載誌

Polymer Chemistry

CiteScore: 8.6

自己引用率: 7.3%

年間論文数: 457

Polymer Chemistry welcomes submissions in all areas of polymer science that have a strong focus on macromolecular chemistry. Manuscripts may cover a broad range of fields, yet no direct application focus is required.

Catalytic chain transfer and its derived macromonomers

文献情報

おすすめジャーナル

関連文献

Robustness and accuracy improvement of data processing with 2D neural networks for transient absorption dynamics

Identification of intermediates of a molecular ruthenium catalyst for water oxidation using in situ electrochemical X-ray absorption spectroscopy

Unraveling the computed non-least motion pathway for the homodimerization of superchameleonic isocyanides: the peculiar nonsymmetrical (F–NC)2 reactant complex

Phase analysis of tungsten and phonon behavior of beryllium layers in W/Be periodic multilayers

Understanding charge storage in Nb2CTx MXene as an anode material for lithium ion batteries

A graphene–Mo2C heterostructure for a highly responsive broadband photodetector

The disparate effect of strain on thermal conductivity of 2-D materials

Theoretical study of spodium bonding in the active site of three Zn-proteins and several model systems

Generation, contraction, and polarisation of Gaussian basis sets for atomic and molecular calculations using the generator coordinate method with polynomial discretisation: atoms from Na through Cl

Single sheets of graphene for fabrication of fibers with enhanced mechanical properties

こちらもおすすめ

間溴苯甲酰腈の市場動向や研究トレンドはどうですか？

去磺基萝卜硫苷とは何ですか？

Methyl 2-amino-5-(trifluoromethyl)benzoateに適用される法規ガイドラインは何ですか？

3-ブロモ-1,3,4,5-四水化-2H-1-ベンザアゼピン-2-オンは安全ですか？

三氟甲基ピリジン-2-甲アミン塩酸塩は安全ですか？

1-エチル-4-(4-硝基フェニル)ピペリジンは安全ですか？

1,1-ジメトキシプロパン-2-オンは安全ですか？

コバルト(II) 3,3'-{[(1S,2S)-1,2-ジメチルフENCYCLICALE-1,2-エチエンジイル]ビス[ニトロリルメチルイリデン]}ビス[4-オキソ-2-ペンテン-2-olate]について「に適用される法規ガイドラインは何ですか？

「カーバミル酸, N-[8-[[2-[[2-(2,6-ジオキソ-3-ピペリジニル)-2,3-ジオキソ-1,3-ジヒドロ-1H-イソイソインドール-4-イルオキシ]アセチル]アミノ]オクチル]-1,1-ジメチレチルエステル」はどのように保存すればよいですか？

FMoc-D-4-Aph(tBu-CbM)-OHはどのように保存すればよいですか？

掲載誌

Polymer Chemistry

おすすめ化合物

(2E)-3-(3-Cyanophenyl)acrylic acid

3,3-Dimethoxy-2-butanone

5-(2-Phenylpyrazolo[1,5-a]pyridin-3-yl)-2H-pyrazolo[3,4-c]pyridazin-3-amine

(3,4-Difluoro-2-methoxyphenyl)boronic acid

2-Ethoxy-3,4-dihydro-2H-pyran

おすすめサプライヤー