Efficient electrochemical polymerhalogenation using a thin-layered cell

文献情報

出版日 2011-05-07

DOI 10.1039/C1PY00150G

インパクトファクター 5.582

著者

Shotaro Hayashi, Shinsuke Inagi, Toshio Fuchigami

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要旨

The electrochemical halogenation of polythiophene derivatives (PTs) such as poly(3-hexylthiophene) (PHT), poly(thiophene-alt-9,9-dioctylfluorene) (PTF) and poly(bithiophene-alt-9,9-dioctylfluorene) (PBT) was investigated using a thin-layered cell. The reactivity and the current efficiency of the electrochemical halogenation of polythiophene derivatives were markedly improved by using the thin-layered cell as compared to using a conventional beaker-type cell. Moreover, the use of the thin-layered cell reduces the amount of electrolytic solution required. In addition, the optical and electrochemical properties of the obtained polymers were significantly changed by the complete substitution of chlorine atoms onto the thiophene ring.

掲載誌

Polymer Chemistry

CiteScore: 8.6

自己引用率: 7.3%

年間論文数: 457

Polymer Chemistry welcomes submissions in all areas of polymer science that have a strong focus on macromolecular chemistry. Manuscripts may cover a broad range of fields, yet no direct application focus is required.

Efficient electrochemical polymerhalogenation using a thin-layered cell

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