Recent advances in sunlight induced polymerization: role of new photoinitiating systems based on the silyl radical chemistry

文献情報

出版日 2011-03-24

DOI 10.1039/C1PY00073J

インパクトファクター 5.582

著者

Jacques Lalevée, Jean Pierre Fouassier

原文を見る

要旨

In the present paper, the recent development of new silyl chemistry based photoinitiating systems for sunlight induced polymerization is presented. The inherent issues of the effects of a low light intensity and oxygen inhibition are discussed. Some selected examples leading to tack free coatings in free radical photopolymerization (FRP) and cationic photopolymerization (CP) are provided. The use of the silyl radical chemistry to overcome the O2 inhibition is presented. The sunlight induced polymerization might be a promising way for practical low cost and environmentally friendly curing processes. The use of renewable epoxy monomers (such as epoxidized soybean oil (ESO), epoxidized linseed oil (ELO) or limonene dioxide (LDO)) in combination with a sunlight induced process also appears particularly worthwhile for green chemistry applications.

掲載誌

Polymer Chemistry

CiteScore: 8.6

自己引用率: 7.3%

年間論文数: 457

Polymer Chemistry welcomes submissions in all areas of polymer science that have a strong focus on macromolecular chemistry. Manuscripts may cover a broad range of fields, yet no direct application focus is required.

Recent advances in sunlight induced polymerization: role of new photoinitiating systems based on the silyl radical chemistry

文献情報

おすすめジャーナル

関連文献

Neural network force fields for simple metals and semiconductors: construction and application to the calculation of phonons and melting temperatures

Electrical conductivity and oxygen diffusion behaviour of the (La0.8Sr0.2)0.95CrxFe1−xO3−δ (x = 0.3, 0.5 and 0.7) A-site deficient perovskites

Asymmetric abstraction of two chemically-equivalent methylene hydrogens: significant enantioselectivity of endoperoxide presented by fumitremorgin B endoperoxidase

Magnetic-field-tuned phase transition of a molecular material from the isolated-spin to the coupled-spin regime

Spectroscopic characterisation of centropolyindanes

Thermoelectric properties of the tetrahedrite–tennantite solid solutions Cu12Sb4−xAsxS13 and Cu10Co2Sb4−yAsyS13 (0 ≤ x, y ≤ 4)

Growth of nanodroplets on a still microfiber under flow conditions

A detailed insight into the catalytic reduction of NO operated by Cr–Cu nanostructures embedded in a CeO2 surface

The role of the dihedral angle and excited cation states in ionization and dissociation of mono-halogenated biphenyls; a combined experimental and theoretical coupled cluster study

Electronic and magnetic properties of CoPc and FePc molecules on graphene: the substrate, defect, and hydrogen adsorption effects

こちらもおすすめ

3-(2-オキサプロピル)ベンzoic酸はどのように合成されますか？

BOC-L-3-氟苯丙氨酸の主な用途は何ですか？

4-メチル-4-ピペリジニル-1-ピロリドイン甲酸の主な用途は何ですか？

Biotin-PEG3-oxyamine HCl塩について、適切な化合物名称に適用される法規ガイドラインは何ですか？

N-(4-イソチオシアネートフェニル)-2-メトキシアリニンはどのように合成されますか？

金粉蕨亭2'-O-葡萄糖甙の主な用途は何ですか？

2-(2-ニトロフェニル)酢酸ヒドライドの物理化学的性質は何ですか？

5-(ヒドロキシメチル)-2-チオキソ-2,3-ジヒドロピリミジン-4(1H)-オンを取り扱う際の実験室安全事項は何ですか？

11-脱氢血栓烷 b2の市場動向や研究トレンドはどうですか？

3,3-二甲基哌啶-4-酮はどのように保存すればよいですか？

掲載誌

Polymer Chemistry

おすすめ化合物

3-(3-Methoxybenzyl)pyrrolidine-2,5-dione

2-Isopropoxybenzaldehyde

[4-Chloro-3-(diethylcarbamoyl)phenyl]boronic acid

3-(4-Bromoanilino)-3-oxopropanoic acid

2-Propanol, 1,3-bis(1-naphthalenyloxy)-

おすすめサプライヤー