Near-critical water, a cleaner solvent for the synthesis of a metal–organic framework
文献情報
Ilich A. Ibarra, Peter A. Bayliss, Eduardo Pérez, Sihai Yang, Alexander J. Blake, Harriott Nowell, David R. Allan, Martyn Poliakoff, Martin Schröder
The microporous metal–organic framework {[Zn2(L)]·(H2O)3}∞ (H4L = 1,2,4,5-tetrakis(4-carboxyphenyl)benzene) has been synthesised using near-critical water (300 °C) as a cleaner alternative to toxic organic solvents. A single crystal X-ray structure determination confirms that the complex incorporates tetrahedral Zn(II) centres bridged through the carboxylate anions to form a binuclear building block, which extends into a one dimensional chain along the c axis. Four L4− ligands bind to each Zn(II) centre and cross-link the one dimensional chains along both a and b axes to afford a three dimensional network structure incorporating pores of ca. 4.3 Å in diameter. The complex shows high thermal stability up to 425 °C by gravimetric thermal analysis, and on desolvation, displays a high adsorption enthalpy of 11.0 kJ mol−1 for H2 uptake at zero coverage, consistent with the narrow pore diameter for the framework.
関連文献
Theoretical study of electronic and tribological properties of h-BNC2/graphene, h-BNC2/h-BN and h-BNC2/h-BNC2 bilayers
Narjes Ansari, Francesc Illas
DOI: 10.1039/C5CP00381D
In silico prediction of MOFs with high deliverable capacity or internal surface area
Yi Bao, Richard L. Martin, Maciej Haranczyk
DOI: 10.1039/C5CP00002E
Influence of the interface in quantum corrections on the low-temperature resistance of La2/3Sr1/3MnO3 trilayer masking thin films
Yuan Jin, Xiao-Peng Cui, Wei-Hua Han, Shi-Xun Cao, Yu-Ze Gao, Jin-Cang Zhang
DOI: 10.1039/C5CP00842E
Physical chemistry and membrane properties of two phosphatidylinositol bisphosphate isomers
Yu-Hsiu Wang
DOI: 10.1039/C5CP00862J
Towards multielectron photocatalysis: a porphyrin array for lateral hole transfer and capture on a metal oxide surface
Bradley J. Brennan, Alec C. Durrell, Matthieu Koepf, Robert H. Crabtree, Gary W. Brudvig
DOI: 10.1039/C5CP01683E
Local strain effect on the thermal transport of graphene nanoribbons: a molecular dynamics investigation
Lanqing Xu, Xiaoman Zhang, Yongping Zheng
DOI: 10.1039/C4CP06014H
The histone H3 N-terminal tail: a computational analysis of the free energy landscape and kinetics
Yuqing Zheng
DOI: 10.1039/C5CP01858G
Self-assembly and coverage dependent thermally induced conformational changes of Ni(ii)-meso-tetrakis (4-tert-butylphenyl) benzoporphyrin on Cu(111)
DOI: 10.1039/C5CP01490E
The electronic states of a double carbon vacancy defect in pyrene: a model study for graphene
Francisco B. C. Machado
DOI: 10.1039/C4CP05751A
Alternative mechanisms for O2 release and O–O bond formation in the oxygen evolving complex of photosystem II
Per E. M. Siegbahn
DOI: 10.1039/C5CP00138B
こちらもおすすめ
オステニ二甲磺酸塩に適用される法規ガイドラインは何ですか?
オステニ二甲磺酸塩は、GHS分類に基づき corrosive 物質として分類されます。REACH規則では、該当物質の登録が要求される可能性があります。また、FD...
環丁基肼盐酸盐は安全ですか?
環丁基肼盐酸盐は毒性があり、吸入や皮膚接触は有害です。使用時の安全対策として、密閉システムを使用し、適切な排気設備を備えた場所で作業することが推奨されます。
N-(4-パリドン基ソニルフェニル)硫代イソシアネートを取り扱う際の実験室安全事項は何ですか?
N-(4-パリドン基ソニルフェニル)硫代イソシアネートは高毒性で、皮膚や吸入による毒性があります。取り扱う際は防毒マスク、保護用手袋、保護眼鏡などのPPEを着用...
5-ヒドロキシ-1,3-ジヒドロ-2H-インドン-2-酮の物理化学的性質は何ですか?
CAS番号3416-18-0の5-ヒドロキシ-1,3-ジヒドロ-2H-インドン-2-酮は、結晶性の白色粉末です。分子量は228.25であり、 aqueous m...
O-苄基-D-丝氨醇はどのように合成されますか?
O-苄基-D-丝氨醇は、D-アミノ酸とベンゼン環の経由で合成されます。触媒としてジメチルアミノピリジンが使用され、選択性は高いです。一般的な収率は約90%です。
ナトリウム3-ヒドロキシbutano酸とは何ですか?
ナトリウム3-ヒドロキシbutano酸は、CAS番号13613-65-5で登録されている化合物です。この化合物は、(3R)-3-ヒドロキシbutano酸とナトリ...
1-(二苯甲基)-4-甲基ベンゼンの物理化学的性質は何ですか?
CAS番号603-37-2の1-(二苯甲基)-4-甲基ベンゼンは、結晶性の固体で、分子量は244.28であり、水中的には微溶です。この化合物は有機反応において中...
ネアミン塩酸塩の物理化学的性質は何ですか?
ネアミン塩酸塩の分子量は321.19であり、結晶性の白色粉末です。この化合物は水に溶けやすく、pHが低くなると不溶性になります。反応活性は高く、水溶液中の酸化還...
偶氮二甲酰二哌啶の主な用途は何ですか?
偶氮二甲酰二哌啶は、医薬品、染料、高 Então 剤、触媒、溶媒、量論試薬など、様々な分野で使用されています。特に、高 Enough 反応において、グリコール酸...
掲載誌
Green Chemistry

Green Chemistry provides a unique forum for the publication of innovative research on the development of alternative green and sustainable technologies. The scope of Green Chemistry is based on, but not limited to, the definition proposed by Anastas and Warner (Green Chemistry: Theory and Practice, P T Anastas and J C Warner, Oxford University Press, Oxford, 1998). Green chemistry is the utilisation of a set of principles that reduces or eliminates the use or generation of hazardous substances in the design, manufacture and application of chemical products. Green Chemistry is at the frontiers of this continuously-evolving interdisciplinary science and publishes research that attempts to reduce the environmental impact of the chemical enterprise by developing a technology base that is inherently non-toxic to living things and the environment. Submissions on all aspects of research relating to the endeavour are welcome. The journal publishes original and significant cutting-edge research that is likely to be of wide general appeal. To be published, work must present a significant advance in green chemistry. Papers must contain a comparison with existing methods and demonstrate advantages over those methods before publication can be considered. For more information please see this Editorial. Coverage includes the following, but is not limited to: Design (e.g. biomimicry, design for degradation/recycling/reduced toxicity…) Reagents & Feedstocks (e.g. renewables, CO2, solvents, auxiliary agents, waste utilization…) Synthesis (e.g. organic, inorganic, synthetic biology…) Catalysis (e.g. homogeneous, heterogeneous, enzyme, whole cell…) Process (e.g. process design, intensification, separations, recycling, efficiency…) Energy (e.g. renewable energy, fuels, photovoltaics, fuel cells, energy storage, energy carriers…) Applications (e.g. electronics, dyes, consumer products, coatings, pharmaceuticals, preservatives, building materials, chemicals for industry/agriculture/mining…) Impact (e.g. safety, metrics, LCA, sustainability, (eco)toxicology…) Green chemistry is, by definition, a continuously-evolving frontier. Therefore, the inclusion of a particular material or technology does not, of itself, guarantee that a paper is suitable for the journal. To be suitable, the novel advance should have the potential for reduced environmental impact relative to the state of the art. Green Chemistry does not normally deal with research associated with 'end-of-pipe' or remediation issues.











![5-Chloropyrrolo[2,1-f][1,2,4]triazin-4(3H)-one structure 5-Chloropyrrolo[2,1-f][1,2,4]triazin-4(3H)-one structure](https://static.chemtradehub.com/structs/888/888720-60-3-4f7c.webp)
![4-Fluoro-2-(4-{[(3S,4R)-4-(2-hydroxy-2-propanyl)-3-pyrrolidinyl]amino}-6,7-dimethoxy-2-quinazolinyl)phenol hydrochloride (1:1) structure 4-Fluoro-2-(4-{[(3S,4R)-4-(2-hydroxy-2-propanyl)-3-pyrrolidinyl]amino}-6,7-dimethoxy-2-quinazolinyl)phenol hydrochloride (1:1) structure](https://static.chemtradehub.com/structs/143/1431697-96-9-619c.webp)

