XPS revelation of tungsten edges as a potential donor-type catalyst

文献情報

出版日 2011-06-14

DOI 10.1039/C1CP21421G

インパクトファクター 3.676

著者

Yanguang Nie, Xi Zhang, Shouzhi Ma, Yan Wang, Jisheng Pan

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要旨

We report an efficient yet simple technology of photoelectron spectroscopic purification for identifying the capability of, and direction of charge flow in, a catalyst in a reaction, which has enabled the finding, for the first time, of the similarity of the valence band of tungsten edges to that of Rh adatoms and Ag/Pd alloy and hence suggested that W undercoordinated atoms could be a suitable candidate for replacing the costly Rh adatoms and Ag/Pd alloy as a cheaper, richer, and efficient donor-type catalyst for CO and NO oxidation applications. The new technology and new findings will be stimulating to the community for new catalyst design and identification and provide a better understanding of the electronic process of a catalytic reaction associated with undercoordinated atoms.

掲載誌

Physical Chemistry Chemical Physics

CiteScore: 5.5

自己引用率: 10.3%

年間論文数: 3036

Physical Chemistry Chemical Physics (PCCP) is an international journal co-owned by 19 physical chemistry and physics societies from around the world. This journal publishes original, cutting-edge research in physical chemistry, chemical physics and biophysical chemistry. To be suitable for publication in PCCP, articles must include significant innovation and/or insight into physical chemistry; this is the most important criterion that reviewers and Editors will judge against when evaluating submissions. The journal has a broad scope and welcomes contributions spanning experiment, theory, computation and data science. Topical coverage includes spectroscopy, dynamics, kinetics, statistical mechanics, thermodynamics, electrochemistry, catalysis, surface science, quantum mechanics, quantum computing and machine learning. Interdisciplinary research areas such as polymers and soft matter, materials, nanoscience, energy, surfaces/interfaces, and biophysical chemistry are welcomed if they demonstrate significant innovation and/or insight into physical chemistry. Joined experimental/theoretical studies are particularly appreciated when complementary and based on up-to-date approaches.