A statistical approach to inelastic electron tunneling spectroscopy on fullerene-terminated molecules
文献情報
Jakob Kryger Sørensen, Emanuel Lörtscher, Tom Vosch, Heike Riel, Kristine Kilså, Thomas Bjørnholm, Herre van der Zant
We report on the vibrational fingerprint of single C60 terminated molecules in a mechanically controlled break junction (MCBJ) setup using a novel statistical approach manipulating the junction mechanically to address different molecular configurations and to monitor the corresponding vibrational modes. In the IETS spectra, the vibrations of the anchoring C60 dominate the spectra; thus information on the unit anchored with C60 to the electrodes is masked by the modes arising from the anchoring groups. However, we have identified the additional modes from the fluorene backbone optically.
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Physical Chemistry Chemical Physics (PCCP) is an international journal co-owned by 19 physical chemistry and physics societies from around the world. This journal publishes original, cutting-edge research in physical chemistry, chemical physics and biophysical chemistry. To be suitable for publication in PCCP, articles must include significant innovation and/or insight into physical chemistry; this is the most important criterion that reviewers and Editors will judge against when evaluating submissions. The journal has a broad scope and welcomes contributions spanning experiment, theory, computation and data science. Topical coverage includes spectroscopy, dynamics, kinetics, statistical mechanics, thermodynamics, electrochemistry, catalysis, surface science, quantum mechanics, quantum computing and machine learning. Interdisciplinary research areas such as polymers and soft matter, materials, nanoscience, energy, surfaces/interfaces, and biophysical chemistry are welcomed if they demonstrate significant innovation and/or insight into physical chemistry. Joined experimental/theoretical studies are particularly appreciated when complementary and based on up-to-date approaches.













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