A fully self-assembled non-symmetric triad for photoinduced charge separation

文献情報

出版日 2010-12-24

DOI 10.1039/C0SC00520G

インパクトファクター 9.825

著者

G. Dan Pantoş, Jeremy K. M. Sanders, Michele Orlandi, Claudio Chiorboli, Sandro Fracasso

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要旨

A very efficient and successful metal-mediated strategy towards the formation of a non-symmetric triad is described: appropriate Lewis acid and/or base functions on the molecular components (a naphthalenediimide, an aluminium(III) porphyrin, and a ruthenium(II) porphyrin) lead to the desired product uniquely. The photophysics of the triad was investigated in detail using time-resolved spectroscopy in the pico- and nanosecond time domains. The strategy is of great potential interest as, while confining the synthetic effort to the single components, it can give access to a wide range of photoactive systems.

掲載誌

Chemical Science

CiteScore: 14.4

自己引用率: 3.9%

年間論文数: 1413

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A fully self-assembled non-symmetric triad for photoinduced charge separation

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