Metalloenzymatic radical polymerization using alkyl halides as initiators

文献情報

出版日 2010-09-25

DOI 10.1039/C0PY00139B

インパクトファクター 5.582

著者

Yeap-Hung Ng, Fabio di Lena, Christina L. L. Chai

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要旨

A novel initiation strategy for enzyme-induced radical polymerization that makes use of alkyl halides is reported here. The approach is remarkably versatile and can be applied to emulsion polymerization as well as surface-initiated polymerization. The molecular weights of the polymers can be effectively regulated with either irreversible (i.e., L-cysteine) or reversible (i.e., 2-cyano-2-propyl dithiobenzoate) chain transfer agents, the latter resulting in a well-controlled, RAFT-type polymerization process.

掲載誌

Polymer Chemistry

CiteScore: 8.6

自己引用率: 7.3%

年間論文数: 457

Polymer Chemistry welcomes submissions in all areas of polymer science that have a strong focus on macromolecular chemistry. Manuscripts may cover a broad range of fields, yet no direct application focus is required.

Metalloenzymatic radical polymerization using alkyl halides as initiators

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