Dispersion nitroxide mediated polymerization of methyl methacrylate in supercritical carbon dioxide using in situ formed stabilizers

文献情報

出版日 2010-04-13

DOI 10.1039/C0PY00066C

インパクトファクター 5.582

著者

Bruno Grignard, Trang Phan, Denis Bertin, Didier Gigmes, Christine Jérôme, Christophe Detrembleur

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要旨

Controlled dispersion nitroxide mediated polymerization (NMP) of methyl methacrylate (MMA) was successfully carried out in supercritical carbon dioxide (scCO2) in the presence of a CO2-philic perfluorinated stabilizer generated “in situ”. This is an efficient green approach for preparing free flowing PMMA powder consisting of small sized microspheres.

掲載誌

Polymer Chemistry

CiteScore: 8.6

自己引用率: 7.3%

年間論文数: 457

Polymer Chemistry welcomes submissions in all areas of polymer science that have a strong focus on macromolecular chemistry. Manuscripts may cover a broad range of fields, yet no direct application focus is required.

Dispersion nitroxide mediated polymerization of methyl methacrylate in supercritical carbon dioxide using in situ formed stabilizers

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