Highly efficient, stoichiometric radical exchange reactions using isoindoline profluorescent nitroxides

文献情報

出版日 2010-05-08

DOI 10.1039/C0PY00015A

インパクトファクター 5.582

著者

Kathryn E. Fairfull-Smith, Aaron S. Micallef, Steven E. Bottle*

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要旨

Exchange reactions between the isoindoline profluorescent nitroxide 1,1,3,3-tetramethyldibenzo[e,g]isoindolin-2-yloxyl (TMDBIO) and a TEMPO capped polystyrene were carried out. High conversions to the desired products were achieved using only stoichiometric ratios of nitroxide relative to polymer. The scope of this study was expanded by exploiting a di-nitroxide 9,10-bis(5-[1,1,3,3-tetramethylisoindolin-2-yloxy])anthracene (BTMIOA) as a connector between two polymer chains forming PS–nitroxide–PS systems.

掲載誌

Polymer Chemistry

CiteScore: 8.6

自己引用率: 7.3%

年間論文数: 457

Polymer Chemistry welcomes submissions in all areas of polymer science that have a strong focus on macromolecular chemistry. Manuscripts may cover a broad range of fields, yet no direct application focus is required.

Highly efficient, stoichiometric radical exchange reactions using isoindoline profluorescent nitroxides

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