Syntheses, structural characterization and CO releasing properties of boranocarbonate [H3BCO2H]− derivatives

文献情報

出版日 2010-08-24

DOI 10.1039/C0OB00099J

インパクトファクター 3.876

著者

Tamil Selvi Pitchumony, Bernhard Spingler, Roberto Motterlini, Roger Alberto

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要旨

CO plays an important role in biological processes and molecules which release CO in a controllable way could therefore be used for medicinal purposes. Beside organometallic carbonyl complexes, boranocarbonate [H3BCO2H]− is one of the most promising candidates but releases CO too rapidly. In order to delay the CO release, we have prepared boranocarbamates [H3BCONH-R]− from [H3BCO2H]− which comprise histamine, morpholine, aniline and ethylene-diamine bound via amides to the {H3BCO} moiety. The syntheses of the new derivatives is described together with their structural characterization. These compounds release CO at a much slower rate than the parent compound and are therefore potential CO releasing molecules for biological and medicinal application.

掲載誌

Organic & Biomolecular Chemistry

CiteScore: 3.4

自己引用率: 10.3%

年間論文数: 1041

Organic & Biomolecular Chemistry (OBC) publishes original and high impact research and reviews in organic chemistry. We welcome research that shows new or significantly improved protocols or methodologies in total synthesis, synthetic methodology or physical and theoretical organic chemistry as well as research that shows a significant advance in the organic chemistry or molecular design aspects of chemical biology, catalysis, supramolecular and macromolecular chemistry, theoretical chemistry, mechanism-oriented physical organic chemistry, medicinal chemistry or natural products. Articles published in the journal should report new work which makes a highly-significant impact in the field. Routine and incremental work is generally not suitable for publication in the journal. More details about key areas of our scope are below. In all cases authors should include in their article clear rationale for why their research has been carried out.

Syntheses, structural characterization and CO releasing properties of boranocarbonate [H3BCO2H]− derivatives

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