Eley–Rideal recombination of hydrogen atoms on a tungsten surface
文献情報
M. Rutigliano, M. Cacciatore
The Eley–Rideal recombination reaction of H chemisorbed on the four-fold site of W(001) at a surface temperature TS = 500 K is studied using the fully three-dimensional semiclassical collisional model and an accurate potential energy surface for the H–W(001) system. The recombination probability, calculated at different collisional energies in the range (0.05–5) eV, shows a broad maximum around 0.4 for energies between 0.1 eV and 2.5 eV. The exothermic energy partitioning in the final states of the desorbing H2 molecules shows that, at low impact energies, only the first three vibrational levels of the hydrogen molecule are energetically accessible, while at the higher impact energies vibrational levels up to v = 7 can be populated. The energy exchanged with the phonons surface is small but not negligible.
おすすめジャーナル

Science Progress

Pharmacological Reviews

Journal of Organometallic Chemistry

Proceedings of the National Academy of Sciences of the United States of America

Organic Preparations and Procedures International

Helvetica Chimica Acta

Journal of Medicinal Chemistry

Russian Chemical Reviews

Pure and Applied Chemistry

Science
関連文献
Plasmon-enhanced homogeneous and heterogeneous triplet–triplet annihilation by gold nanoparticles
Xian Cao, Bo Hu, Rui Ding, Peng Zhang
DOI: 10.1039/C5CP01876E
Origin of enhanced visible light driven water splitting by (Rh, Sb)-SrTiO3
Brindaban Modak, Swapan K. Ghosh
DOI: 10.1039/C5CP01374G
Singlet ground state actinide chemistry with geminals
Paweł Tecmer, Katharina Boguslawski, Paul W. Ayers
DOI: 10.1039/C4CP05293E
Peculiar morphological transitions induced by nanoparticles in polymeric blends: retarded relaxation or altered interfacial tension?
Shital Patangrao Pawar, Suryasarathi Bose
DOI: 10.1039/C5CP01644D
Structure and segregation of dopant–defect complexes at grain boundaries in nanocrystalline doped ceria
Pratik P. Dholabhai, Jeffery A. Aguiar, Longjia Wu, Terry G. Holesinger, Toshihiro Aoki, Ricardo H. R. Castro, Blas P. Uberuaga
DOI: 10.1039/C5CP02200B
Electronic couplings for molecular charge transfer: benchmarking CDFT, FODFT and FODFTB against high-level ab initio calculations. II
Adam Kubas, Fruzsina Gajdos, Harald Oberhofer, Jochen Blumberger
DOI: 10.1039/C4CP04749D
Scaling of anomalous Hall effects in facing-target reactively sputtered Fe4N films
Y. Zhang, W. B. Mi, X. C. Wang, X. X. Zhang
DOI: 10.1039/C5CP01955A
Kinks in experimental diffusion profiles of a dissolving semi-crystalline polymer explained by a concentration-dependent diffusion coefficient
Helen E. Hermes, Christoph E. Sitta, Burkhard Schillinger, Hartmut Löwen, Stefan U. Egelhaaf
DOI: 10.1039/C5CP01082A
Elucidating the mechanism of interaction between peptides and inorganic surfaces
David Zanuy
DOI: 10.1039/C5CP00088B
To what extent can charge localization influence electron injection efficiency at graphene–porphyrin interfaces?
Manas R. Parida, Shawkat M. Aly, Erkki Alarousu, Aravindan Sridharan, Doddahalli H. Nagaraju, Husam N. Alshareef, Omar F. Mohammed
DOI: 10.1039/C5CP02362A
こちらもおすすめ
6-苄基-6,7-二氢-5H-吡咯并3,4-b吡啶とは何ですか?
6-苄基-6,7-二氢-5H-吡咯并3,4-b吡啶は、CAS番号109966-30-5の化合物です。これは、6-ベンジル基を持つ6,7-二氢-5H-吡咯並みの化...
半硫酸奎宁单水水合物はどのように保存すればよいですか?
半硫酸奎宁单水水合物は、乾燥した涼しい場所に保管し、直射日光や湿気を避ける必要があります。保存温度は常温(15〜25℃)が適切で、湿度は40%以下を維持すること...
D-核糖-5-リン酸二ナトリウムとは何ですか?
D-核糖-5-リン酸二ナトリウムは、CAS番号18265-46-8を有する化合物で、D-核糖の5位付加部位にリン酸基が結合した化合物です。この化合物は、水溶性で...
3-乙酰基-4-羟基喹啉-2(1H)-酮はどのように合成されますか?
3-乙酰基-4-羟基喹啉-2(1H)-酮は、ハイドロキノンと酢酸アセトイルアミドのアミド化反応により合成されます。この反応は塩基触媒を用いて行われ、選択性は良好...
5-溴-4-甲基-1H-吲唑とは何ですか?
5-溴-4-甲基-1H-吲唑は、CAS番号1082041-34-6の化学物質で、化学式はC10H9BrNです。この化合物は淡黄色の結晶性粉末で、吸湿性があります...
3-(4メトキシフェニル)オキテナン-3カーボイル酸の代替品はありますか?
3-(4メトキシフェニル)オキテナン-3カーボイル酸の代替品は、その用途により異なりますが、例えば4-(メトキシフェニル)オキテナン-3カーボイル酸や、他のオキ...
3-イリドオキシピロロ[2,3-b]ピリジン-5-カルボキシlic酸は安全ですか?
3-イリドオキシピロロ[2,3-b]ピリジン-5-カルボキシlic酸は危険な化合物ではありませんが、適切な手袋や保護眼鏡の使用を推奨します。誤って摂取または接触...
3-氟-4- iodobenolを取り扱う際の実験室安全事項は何ですか?
3-氟-4- iodobenolは可燃性を有し、強力な反応性を持つため、取り扱いには注意が必要です。PPE(個人保護具)の着用、ドラフトチャンバーの使用、漏洩時...
掲載誌
Physical Chemistry Chemical Physics

Physical Chemistry Chemical Physics (PCCP) is an international journal co-owned by 19 physical chemistry and physics societies from around the world. This journal publishes original, cutting-edge research in physical chemistry, chemical physics and biophysical chemistry. To be suitable for publication in PCCP, articles must include significant innovation and/or insight into physical chemistry; this is the most important criterion that reviewers and Editors will judge against when evaluating submissions. The journal has a broad scope and welcomes contributions spanning experiment, theory, computation and data science. Topical coverage includes spectroscopy, dynamics, kinetics, statistical mechanics, thermodynamics, electrochemistry, catalysis, surface science, quantum mechanics, quantum computing and machine learning. Interdisciplinary research areas such as polymers and soft matter, materials, nanoscience, energy, surfaces/interfaces, and biophysical chemistry are welcomed if they demonstrate significant innovation and/or insight into physical chemistry. Joined experimental/theoretical studies are particularly appreciated when complementary and based on up-to-date approaches.
![1H-Imidazo[4,5-c]pyridine-7-carboxylic acid structure 1H-Imidazo[4,5-c]pyridine-7-carboxylic acid structure](https://static.chemtradehub.com/structs/123/1234616-39-7-1344.webp)
![[1-(5-Methyl-2-pyridinyl)-1H-pyrazol-4-yl]methanol structure [1-(5-Methyl-2-pyridinyl)-1H-pyrazol-4-yl]methanol structure](https://static.chemtradehub.com/structs/143/1439822-99-7-6cc9.webp)


