Guiding the time-evolution of a molecule: optical control by computer
文献情報
Graham A. Worth, Cristina Sanz Sanz
The theory and computation of optical control has been developed over the last 25 years and is now a mature field of research. Initial work provided pictures of how control using light fields in simple systems may be achieved, for example using multiple excitation pathways or pulse sequences. The development of optimal control theory then provided a general method for guiding a system to its target using a shaped laser pulse. Combined with quantum dynamics simulations this has become a widely used tool, and has been applied to a range of systems to show what can be controlled. The present challenge is to gain more insight into the mechanism of control. In addition, methods need to be extended to reach the size of system of interest to technology. In this perspective article we shall give a brief overview of present capabilities and some of the recent developments in quantum dynamics and control simulations.
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掲載誌
Physical Chemistry Chemical Physics

Physical Chemistry Chemical Physics (PCCP) is an international journal co-owned by 19 physical chemistry and physics societies from around the world. This journal publishes original, cutting-edge research in physical chemistry, chemical physics and biophysical chemistry. To be suitable for publication in PCCP, articles must include significant innovation and/or insight into physical chemistry; this is the most important criterion that reviewers and Editors will judge against when evaluating submissions. The journal has a broad scope and welcomes contributions spanning experiment, theory, computation and data science. Topical coverage includes spectroscopy, dynamics, kinetics, statistical mechanics, thermodynamics, electrochemistry, catalysis, surface science, quantum mechanics, quantum computing and machine learning. Interdisciplinary research areas such as polymers and soft matter, materials, nanoscience, energy, surfaces/interfaces, and biophysical chemistry are welcomed if they demonstrate significant innovation and/or insight into physical chemistry. Joined experimental/theoretical studies are particularly appreciated when complementary and based on up-to-date approaches.












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