A method to tune the ionic current rectification of track-etched nanopores by using surfactant
文献情報
Lin Wang, Yu Yan, Yanbo Xie, Long Chen
A method is reported here to tune the ionic current rectification behavior through a conical nanopore fabricated with the track-etching technique. In order to change the surface charge property of the pore wall, we added the cationic surfactant hexadecyl trimethylammonium bromide (CTAB) into the working electrolyte of 0.1 M KCl. By controlling the modified region and the concentration of CTAB, the ionic current rectification degree of the nanopore could be tuned over the wide range of 0.2–65 at the voltage of ±0.9 V. The mechanism of the changes in current rectification behavior was analyzed by numerically solving the Poison–Nernst–Planck (PNP) equations.
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