Structural and hygroscopic changes of soot during heterogeneous reaction with O3

文献情報

出版日 2010-07-23

DOI 10.1039/C0CP00402B

インパクトファクター 3.676

著者

Yongchun Liu, Chang Liu, Jinzhu Ma, Qingxin Ma, Hong He

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要旨

Soot aerosols are ubiquitous in the atmosphere and play an important role in global and regional radiative balance and climate. Their environmental impact, however, greatly depends on their structure, composition, particle size, and morphology. In this study, the structural changes of a model soot (Printex U) during a heterogeneous reaction with 80 ppm O3 at 298 K were investigated using in situ Raman spectroscopy, in situ diffuse reflectance infrared Fourier transform spectroscopy (DRIFTS), and transmission electron microscopy (TEM). Hygroscopic changes due to heterogeneous reaction with O3 were also studied by water sorption analyzer. The consumption of amorphous carbon (D3 band) and disordered graphitic lattice (D4 band) of soot by ozonization was confirmed by the decrease in the full widths at half maximum and their relative integrated intensities (percentages of integrated areas). Oxygen containing surface species including ketone, lactone, and anhydride were also observed in Raman and IR spectra of ozonized soot. The ozonized soot showed more compacted aggregates with a smaller average diameter of primary particles (29.9 ± 7.7 nm) and a larger fractal dimension (1.81 ± 0.08) when compared with fresh soot (36.9 ± 9.4 nm, and 1.61 ± 0.10). The ozonization reaction leads to an enhancement of hygroscopicity of soot due to the decrease in particle diameter and the formation of oxygen containing surface species.

掲載誌

Physical Chemistry Chemical Physics

CiteScore: 5.5

自己引用率: 10.3%

年間論文数: 3036

Physical Chemistry Chemical Physics (PCCP) is an international journal co-owned by 19 physical chemistry and physics societies from around the world. This journal publishes original, cutting-edge research in physical chemistry, chemical physics and biophysical chemistry. To be suitable for publication in PCCP, articles must include significant innovation and/or insight into physical chemistry; this is the most important criterion that reviewers and Editors will judge against when evaluating submissions. The journal has a broad scope and welcomes contributions spanning experiment, theory, computation and data science. Topical coverage includes spectroscopy, dynamics, kinetics, statistical mechanics, thermodynamics, electrochemistry, catalysis, surface science, quantum mechanics, quantum computing and machine learning. Interdisciplinary research areas such as polymers and soft matter, materials, nanoscience, energy, surfaces/interfaces, and biophysical chemistry are welcomed if they demonstrate significant innovation and/or insight into physical chemistry. Joined experimental/theoretical studies are particularly appreciated when complementary and based on up-to-date approaches.