Fine tuning of emission through the engineering of colloidal crystals
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Jean-François Dechézelles, Tangi Aubert, Fabien Grasset, Stéphane Cordier, Carlos Barthou, Catherine Schwob, Agnès Maître, Renaud A. L. Vallée, Henri Cramail, Serge Ravaine
We describe the preparation and characterization of photonic colloidal crystals from silica spheres with incorporated luminescent [Mo6Br14]2− cluster units. These structures exhibit strong angle-dependent luminescent properties. The incorporation of one or several planar defects in the periodic structures gives rise to the creation of a passband in the stopband. In the energy range of this passband, an increase of the emission intensity has been found.
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