Aerobic oxidation of alcohols catalyzed by rhodium(iii) porphyrin complexes in water: reactivity and mechanistic studies

文献情報

出版日 2010-08-12

DOI 10.1039/C0CC01406K

インパクトファクター 6.222

著者

Lianghui Liu, Mengmeng Yu, Bradford B. Wayland, Xuefeng Fu

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要旨

Selective oxidation of alcohol in water using molecular oxygen as the terminal oxidant is mediated by rhodium porphyrin complexes. Addition of methanol to an aqueous solution of (TSPP)Rh(III) resulted in observation of the key intermediate porphyrin rhodium(III) methoxide species. The activation parameters for βC–H elimination of Rh–alkoxide were evaluated.

掲載誌

Chemical Communications

CiteScore: 8.6

自己引用率: 4.7%

年間論文数: 2458

ChemComm publishes urgent research which is of outstanding significance and interest to experts in the field, while also appealing to the journal’s broad chemistry readership. Our communication format is ideally suited to short, urgent studies that are of such importance that they require accelerated publication. Our scope covers all topics in chemistry, and research at the interface of chemistry and other disciplines (such as materials science, nanoscience, physics, engineering and biology) where there is a significant novelty in the chemistry aspects. Major topic areas covered include: Analytical Chemistry Catalysis Chemical Biology and medicinal chemistry Computational Chemistry and Machine Learning Energy and sustainable chemistry Environmental Chemistry Green Chemistry Inorganic Chemistry Materials Chemistry Nanoscience Organic Chemistry Physical Chemistry Polymer Chemistry Supramolecular Chemistry

Aerobic oxidation of alcohols catalyzed by rhodium(iii) porphyrin complexes in water: reactivity and mechanistic studies

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