State-to-state inelastic scattering of Stark-decelerated OH radicals with Ar atoms
文献情報
Ludwig Scharfenberg, Jacek Kłos, Paul J. Dagdigian, Millard H. Alexander, Gerard Meijer, Sebastiaan Y. T. van de Meerakker
The Stark deceleration method exploits the concepts of charged particle accelerator physics to produce molecular beams with a tunable velocity. These tamed molecular beams offer interesting perspectives for precise crossed beam scattering studies as a function of the collision energy. The method has advanced sufficiently to compete with state-of-the-art beam methods that are used for scattering studies throughout. This is demonstrated here for the scattering of OH radicals (X2Π3/2, J = 3/2, f) with Ar atoms, a benchmark system for the scattering of open-shell molecules with atoms. Parity-resolved integral state-to-state inelastic scattering cross sections are measured at collision energies between 80 and 800 cm−1. The threshold behavior and collision energy dependence of 13 inelastic scattering channels is accurately determined. Excellent agreement is obtained with the cross sections predicted by close-coupling scattering calculations based on the most accurate ab initio OH + Ar potential energy surfaces to date.
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