CO2: a wild solvent, tamed
文献情報
Stephen Cummings, Kieran Trickett, Robert Enick, Julian Eastoe
This article reviews approaches for modification of solvent properties of supercritical carbon dioxide (scCO2), with particular reference to self-assembly of oligomeric and polymeric solute additives. Of special interest are viscosity modifiers for scCO2 based on molecular self-assembly. Background on polymers and surfactants with CO2-compatible functionalities is covered, leading on to the attempts made so far to increase the scCO2 viscosity, which are described in detail. The significance of this field, and the implications a breakthrough could bring environmentally and economically will be addressed.
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