Color-tunable luminescence for Bi3+/Ln3+:YVO4 (Ln = Eu, Sm, Dy, Ho) nanophosphors excitable by near-ultraviolet light
文献情報
Daqin Chen, Yunlong Yu, Ping Huang, Hang Lin, Zhifa Shan, Lingwei Zeng, Anping Yang, Yuansheng Wang
Bi3+/Ln3+:YVO4 nanocrystals with a mean size of 6 nm are prepared through a mixed solvothermal route. With Bi3+ doping, the excitation band corresponding to the Ln3+ emission is shifted from 280 nm to 345 nm, owing to the occurrence of Bi3+ → V5+ metal–metal charge transfer and the subsequent energy transfer to Ln3+ ions. Under near-ultraviolet excitation, the emission color of Bi3+/Ln3+:YVO4 nanophosphors can be easily tuned by changing the Ln3+ ions.
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