Hydrogenstorage reaction over a ternary imide Li2Mg2N3H3

文献情報

出版日 2010-02-24

DOI 10.1039/C000271B

インパクトファクター 3.676

著者

Yongfeng Liu, Chu Liang, Zhijun Wei, Ying Jiang, Mingxia Gao, Hongge Pan, Qidong Wang

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要旨

The reaction details of hydrogen storage process of a ternary imide Li2Mg2N3H3 are elucidated for the first time. It is found that 1 mole of Li2Mg2N3H3 converts to a mixture of Mg(NH2)2–2LiH–MgNH on taking up 2 moles of H2, and that the presence of MgNH in the Mg(NH2)2–2LiH system not only alters the dehydrogenation thermodynamics but also improves the dehydrogenation kinetics.

掲載誌

Physical Chemistry Chemical Physics

CiteScore: 5.5

自己引用率: 10.3%

年間論文数: 3036

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