Oriented growth of the functionalized metal–organic framework CAU-1 on –OH- and –COOH-terminated self-assembled monolayers
文献情報
Florian Hinterholzinger, Camilla Scherb, Tim Ahnfeldt, Norbert Stock, Thomas Bein
The oriented growth of the amino-functionalized metal–organic framework [Al4(OH)2(OCH3)4(H2N-bdc)3]·xH2O (named CAU-1; CAU = Christian-Albrechts-University) on different self-assembled monolayers (SAMs) is reported. Gold substrates were modified with both 16-mercaptohexadecanol and 16-mercaptohexadecanoic acid SAMs and immersed in a pre-treated crystallization solution. The different terminal functionalities and synthesis parameters result in the direct surface growth of CAU-1 crystals along preferred crystallographic orientations. While for the OH-terminated SAMs a preferential attachment of the CAU-1 crystals either in [011] or [002] direction is observed (depending on the reaction conditions), highly oriented crystal growth in [002] orientation was obtained on the carboxylic acid functionalized SAMs.
関連文献
Infrared multiple photon dissociation action spectroscopy of protonated glycine, histidine, lysine, and arginine complexed with 18-crown-6 ether
Christopher P. McNary, Y.-W. Nei, Philippe Maitre, M. T. Rodgers, P. B. Armentrout
DOI: 10.1039/C9CP02265A
Elusive hypervalent phosphorus⋯π interactions: evidence for paradigm transformation from hydrogen to phosphorus bonding at low temperatures
P. K. Sruthi, Shubhra Sarkar, N. Ramanathan, K. Sundararajan
DOI: 10.1039/C9CP01925A
The catalytic mechanism of S-acyltransferases: acylation is triggered on by a loose transition state and deacylation is turned off by a tight transition state
Xia Wang, Grace Mercure Bakanina Kissanga, E. Li, Qiang Li, Jianzhuang Yao
DOI: 10.1039/C9CP02248A
Dynamical fluxionality, multiplicity of structural forms, and electronic properties of the B3Si11 cluster: anion photoelectron spectroscopy and theoretical calculations
Sheng-Jie Lu, Li-Shun Wu, Bao-Hua Yin, Feng Lin, Ming-Yong Chao
DOI: 10.1039/C9CP01752F
Coarse-grained simulation studies on the adsorption of polyelectrolyte complexes upon lipid membranes
DOI: 10.1039/C9CP01448A
Thermal transport in monocrystalline and polycrystalline lithium cobalt oxide
Jinlong He, Lin Zhang, Ling Liu
DOI: 10.1039/C9CP01585J
The performance of adsorption, dissociation and diffusion mechanism of hydrogen on the Ti-doped ZrCo(110) surface
Qingqing Wang, Xianggang Kong, Huilei Han, Ge Sang, Guanghui Zhang, Tao Gao
DOI: 10.1039/C9CP02491C
Enhanced photocatalytic activity of perovskite NaNbO3 by oxygen vacancy engineering
Bian Yang, Jihong Bian, Lei Wang, Jianwei Wang, Yaping Du, Zhiguang Wang, Chao Wu, Yaodong Yang
DOI: 10.1039/C9CP01763A
Computational investigation of a promising Si–Cu anode material
Ksenia A. Ivanichkina
DOI: 10.1039/C9CP01571J
Chemical equilibria of aqueous ammonium–carboxylate systems in aqueous bulk, close to and at the water–air interface
Yina Salamanca Blanco, Önder Topel, Éva G. Bajnóczi, Olle Björneholm, Ingmar Persson
DOI: 10.1039/C9CP02449B
こちらもおすすめ
噻奈普汀乙酯の物理化学的性質は何ですか?
CAS番号66981-77-9の噻奈普汀乙酯は、結晶性白色粉末であり、分子量は476.9 g/molです。この化合物は水に溶けにくく、一般的には有機溶媒で溶解し...
アミピシリン不純物Fとは何ですか?
アミピシリン不純物Fは、CAS番号124774-48-7の化合物です。これは、抗生物質アミピシリンの生産過程で生成される不純物の一つであり、(4S)-2-({[...
イリジウム(I)ヘキサフルオロフォスファートの代替品はありますか?
イリジウム(I)ヘキサフルオロフォスファートの代替品として、他の有機金属化合物や非有機金属化合物が使用されることがあります。具体的には、ダイゾニウム塩や他の金属...
含有3-(苯氧基甲基)苯硼酸频那醇酯の廃棄物はどのように処理すべきですか?
含有3-(苯氧基甲基)苯硼酸频那醇酯の廃棄物は、安全な方法で処理する必要があります。まず、廃棄物を適切な容器に収集し、避けて保管します。次に、専門の廃棄処理業者...
2-甲基辛-1-醇を取り扱う際の実験室安全事項は何ですか?
取り扱う際は、密閉のゴーグルと手袋を着用することが推奨されます。ドラフトチャンバーを使用し、漏洩時には速やかに取り扱いを中止し、適切な排気設備を使用してください...
3α-アセトキノイドコレステロールエステルはどのように保存すればよいですか?
3α-アセトキノイドコレステロールエステルは、常温から低温(0-5℃)の暗所で保存し、密閉容器に入れることで安定性を保つことが推奨されます。また、湿気や酸素から...
2-ぶンジロキシ-4-(トリフルオロメチル)フェノルビノン酸の主な用途は何ですか?
2-ぶンジロキシ-4-(トリフルオロメチル)フェノルビノン酸は、化学合成の触媒としての使用や、医薬品の合成材料としての役割があります。また、特定の合成路線で使用...
(2S,3R)-2-氨基-3-甲基丁二酸はどのように合成されますか?
(2S,3R)-2-氨基-3-甲基丁二酸は、2-ヒドロキシ-3-メチル丁酸とアミノ化反応を行うことで合成されます。触媒としてジクロロメタンが使用され、選択性と収...
1-Benzyl-2-phenyl-1H-imidazoleはどのように保存すればよいですか?
この化合物は常温で避けてください。直射日光を避け、密閉容器で保存し、湿気を防水の容器に入れて保管してください。
掲載誌
Physical Chemistry Chemical Physics

Physical Chemistry Chemical Physics (PCCP) is an international journal co-owned by 19 physical chemistry and physics societies from around the world. This journal publishes original, cutting-edge research in physical chemistry, chemical physics and biophysical chemistry. To be suitable for publication in PCCP, articles must include significant innovation and/or insight into physical chemistry; this is the most important criterion that reviewers and Editors will judge against when evaluating submissions. The journal has a broad scope and welcomes contributions spanning experiment, theory, computation and data science. Topical coverage includes spectroscopy, dynamics, kinetics, statistical mechanics, thermodynamics, electrochemistry, catalysis, surface science, quantum mechanics, quantum computing and machine learning. Interdisciplinary research areas such as polymers and soft matter, materials, nanoscience, energy, surfaces/interfaces, and biophysical chemistry are welcomed if they demonstrate significant innovation and/or insight into physical chemistry. Joined experimental/theoretical studies are particularly appreciated when complementary and based on up-to-date approaches.









![N,N'-1,2-Ethanediylbis[2-(vinylsulfonyl)acetamide] structure N,N'-1,2-Ethanediylbis[2-(vinylsulfonyl)acetamide] structure](https://static.chemtradehub.com/structs/667/66710-66-5-b556.webp)



![N-[(5,6-Dichloro-1H-benzimidazol-2-yl)methyl]-9-(1-methyl-1H-pyrazol-4-yl)-2-(4-morpholinyl)-9H-purin-6-amine structure N-[(5,6-Dichloro-1H-benzimidazol-2-yl)methyl]-9-(1-methyl-1H-pyrazol-4-yl)-2-(4-morpholinyl)-9H-purin-6-amine structure](https://static.chemtradehub.com/structs/238/2387704-62-1-25f4.webp)