An improved chemical model for the quantitative description of the front propagation in the tetrathionate–chlorite reaction
文献情報
Gábor Peintler, György Csekő, Andrea Petz, Attila K. Horváth
It is experimentally proven that the stoichiometry of the tetrathionate–chlorite reaction is 2S4O2−6 + 8½ClO−2 + 6H2O = 8SO2−4 + ClO−3 + 7½Cl− + 12H+ near 1 : 4 molar ratio of the reactants. Re-evaluation of the previously measured front velocity—concentration curves also shows that this stoichiometry along with both the rate equation r = (1.6 × 105 M−3 s−1 [H+]2 + 3.6 × 107 M−4 s−1 [H+]3)[S4O2−6][ClO−2]and the protonation processes existing in the present system allow us to describe the front velocity as a function of the initial concentration of the reactants quantitatively. Some consequences detailed in the conclusions may concern not only uniquely the tetrathionate–chlorite reaction but any front propagation study including H+ as an autocatalyst.
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