Constrained-geometry ruthenium carboranyl complexes and their unique chemical properties

文献情報

出版日 2009-03-17

DOI 10.1039/B901549C

インパクトファクター 6.222

著者

Hao Shen, Zuowei Xie

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要旨

By utilizing the unique electronic and steric properties of the icosahedral carboranyl moiety, a new class of constrained-geometry ruthenium complexes bearing linked cyclopentadienyl–carboranyl ligands has been achieved. They exhibit interesting reactivity patterns, of which some are different from conventional cyclopentadienyl ruthenium complexes. For example, the Cp in the constrained-geometry [η5:σC–Me2C(C5H4)C2B10H10]Ru systems is active and participates in reactions to give C–C coupling products whereas the “CpRu” moiety in CpRu–X is inert and remains intact in the same reactions. The constrained-geometry ligands can also stabilize mononuclear Ru bis(vinylidene) complexes and furnish the Ru–C(cage) to Ru–B(cage) conversion in the presence of H2. This account provides an overview of our recent work in this area.

掲載誌

Chemical Communications

CiteScore: 8.6

自己引用率: 4.7%

年間論文数: 2458

ChemComm publishes urgent research which is of outstanding significance and interest to experts in the field, while also appealing to the journal’s broad chemistry readership. Our communication format is ideally suited to short, urgent studies that are of such importance that they require accelerated publication. Our scope covers all topics in chemistry, and research at the interface of chemistry and other disciplines (such as materials science, nanoscience, physics, engineering and biology) where there is a significant novelty in the chemistry aspects. Major topic areas covered include: Analytical Chemistry Catalysis Chemical Biology and medicinal chemistry Computational Chemistry and Machine Learning Energy and sustainable chemistry Environmental Chemistry Green Chemistry Inorganic Chemistry Materials Chemistry Nanoscience Organic Chemistry Physical Chemistry Polymer Chemistry Supramolecular Chemistry

Constrained-geometry ruthenium carboranyl complexes and their unique chemical properties

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