Separation of a diiminopyridine iron(ii) complex into rac- and meso- diastereoisomers provides evidence for a dual stereoregulation mechanism in propenepolymerization

文献情報

出版日 2008-09-12

DOI 10.1039/B810381J

インパクトファクター 6.222

著者

Antonio Rodríguez-Delgado, Juan Cámpora, A. Marcos Naz, Pilar Palma, Manuel L. Reyes

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要旨

Separation of a diiminopyridine iron(II) complex into its rac- and meso- diastereoisomers provides for first time the opportunity of observing the enantiomorphic site control competing with the chain-end control mechanism in a non-metallocene catalyst system.

掲載誌

Chemical Communications

CiteScore: 8.6

自己引用率: 4.7%

年間論文数: 2458

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Separation of a diiminopyridine iron(ii) complex into rac- and meso- diastereoisomers provides evidence for a dual stereoregulation mechanism in propenepolymerization

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