New ligand platforms for developing the chemistry of the TiN–NR2 functional group and the insertion of alkynes into the N–N bond of a TiN–NPh2 ligand

文献情報

出版日 2007-09-21

DOI 10.1039/B711941K

インパクトファクター 6.222

著者

Jonathan D. Selby, Catherine D. Manley, Marta Feliz, Andrew D. Schwarz, Eric Clot, Philip Mountford

原文を見る

要旨

Two broadly applicable strategies for extending the available ligand platforms of the virtually unexplored terminal TiN–NR2 functional group are described, along with the highly selective room temperature insertion of alkynes into the N–N bond of Ti{MeN(CH2CH2NSiMe3)2}(NNPh2)(py) and the catalytic cis-diamination of PhCCMe by diphenylhydrazine.

掲載誌

Chemical Communications

CiteScore: 8.6

自己引用率: 4.7%

年間論文数: 2458

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