Regioselectivity and enantioselectivity in nickel-catalysed reductive coupling reactions of alkynes

文献情報

出版日 2007-07-03

DOI 10.1039/B707737H

インパクトファクター 6.222

著者

Ryan M. Moslin, Karen Miller-Moslin, Timothy F. Jamison

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要旨

Nickel-catalysed reductive coupling reactions of alkynes have emerged as powerful synthetic tools for the selective preparation of functionalized alkenes. One of the greatest challenges associated with these transformations is control of regioselectivity. Recent work from our laboratory has provided an improved understanding of several of the factors governing regioselectivity in these reactions, and related studies have revealed that the reaction mechanism can differ substantially depending on the ligand employed. A discussion of stereoselective transformations and novel applications of nickel catalysis in coupling reactions of alkynes is also included.

掲載誌

Chemical Communications

CiteScore: 8.6

自己引用率: 4.7%

年間論文数: 2458

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