Magnetic canting or not? Two isomorphous 3D CoII and NiII coordination polymers with the rare non-interpenetrated (10,3)-d topological network, showing spin-canted antiferromagnetism only in the CoII system

文献情報

出版日 2007-03-01

DOI 10.1039/B700569E

インパクトファクター 6.222

著者

Jian-Rong Li, Qun Yu, Ying Tao, Xian-He Bu, Joan Ribas, Stuart R. Batten

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要旨

The in situ solvothermal reaction of 3,4-dicyano-1,2,5-thiadiazole with MCl2 (M = Co, Ni) and NaOH afforded two isomorphous complexes, [M2(L)2(H2O)2]n (L = 2,1,3-thiadiazole-4,5-dicarboxylate), which exhibit a rare non-interpenetrated (10,3)-d (utp) network topology and interesting magnetic behaviors: spin-canted antiferromagnetism for the CoII complex, but simple antiferromagnetic coupling for the NiII.

掲載誌

Chemical Communications

CiteScore: 8.6

自己引用率: 4.7%

年間論文数: 2458

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