Synthesis and characterization of difluoromethylene-homo[60]fullerene, C60(CF2)
文献情報
Anna S. Pimenova, Andrey A. Kozlov, Alexey A. Goryunkov, Vitaliy Yu. Markov, Pavel A. Khavrel, Stanislav M. Avdoshenko, Ilya N. Ioffe, Sergey I. Troyanov, Lev N. Sidorov
Refluxing of the o-DCB solution of C60 with CF2ClCOONa and 18-crown-6 leads to formation of C60(CF2)n (n = 1–3); the monoadduct C60(CF2) has been found to consist of the main [6,6]- and minor [5,6]-isomers, both having an open structure.
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