On the physical nature of mesophases of guanosine gels
文献情報
Laura Rudd, Dominic J. Lee, Alexei A. Kornyshev
The unusual columnar aqueous mesophases of self-assembled guanosine stacks, such as 2′-deoxyguanosine 5′-monophosphate and 2′-deoxyguanosine 3′-monophosphate, are analyzed in terms of a general theory of azimuthal correlations between the charged helices. This theory considers forces, specific to the helical structure of each macromolecule, which depend on the azimuthal orientations of the molecules about their long axes. More specifically, in determining the magnitudes and decay lengths of these helix specific forces we utilize the Kornyshev–Leikin theory of electrostatic interaction between helical macromolecules and quantitatively fit experimental data. Together with explaining a number of the observed features of these mesophases, several new effects are predicted. Possible limitations and developments of our theoretical model are discussed, as well as new experiments to test the implications of the theory.
おすすめジャーナル

Russian Journal of General Chemistry

Current Opinion in Solid State & Materials Science

Chemical Communications

Journal of Peptide Science

Journal of Natural Medicines

Acta Materialia

Russian Journal of Organic Chemistry

Russian Journal of Bioorganic Chemistry

Saudi Pharmaceutical Journal

Russian Journal of Applied Chemistry
関連文献
A physico-chemical investigation of highly concentrated potassium acetate solutions towards applications in electrochemistry
Pierre L. Stigliano, Nicolò Pianta, Simone Bonizzoni, Michele Mauri, Roberto Simonutti, Roberto Lorenzi, Barbara Vigani, Vittorio Berbenni, Silvia Rossi
DOI: 10.1039/D0CP04151C
Theoretical evidence of the spin–valley coupling and valley polarization in two-dimensional MoSi2X4 (X = N, P, and As)
Haoqiang Ai, Di Liu, Jiazhong Geng, Shuangpeng Wang, Kin Ho Lo
DOI: 10.1039/D0CP05926A
Temperature and pressure-induced strains in anhydrous iron trifluoride polymorphs
M. Recio-Poo, A. Lobato, A. Otero-de-la-Roza, M. A. Salvadó, M. E. Arroyo-de Dompablo, J. M. Recio
DOI: 10.1039/D0CP05888B
An oxygen-passivated vanadium cluster [V@V10O15]− with metal–metal coordination produced by reacting Vn− with O2
Miao Yan, Si-Dian Li
DOI: 10.1039/D0CP05385F
Evaluation of the Pr + O → PrO+ + e− chemi-ionization reaction enthalpy and praseodymium oxide, carbide, dioxide, and carbonyl cation bond energies
Maryam Ghiassee, Brandon C. Stevenson, P. B. Armentrout
DOI: 10.1039/D0CP06252A
Redox-couple investigations in Si-doped Li-rich cathode materials
Leah Nation, Yan Wu, Xiaoming Liu, Miaofang Chi, Yuqin Wu, Yue Qi, Brian W. Sheldon
DOI: 10.1039/D0CP05737A
Reactivity of dicationic N-heterocyclic chalcogen carbene analogues with methane and ethene: a theoretical investigation
Tsung-Lung Li, Zheng-Feng Zhang
DOI: 10.1039/D0CP06173E
A simple strategy to overcome concentration dependence of photoswitching properties in donor–acceptor Stenhouse adducts
Sean W. Connolly, Simon J. Holder, Helena J. Shepherd
DOI: 10.1039/D0CP06312F
Photoelectron spectroscopy and theoretical study of AlnC5−/0 (n = 1–5) clusters: structural evolution, relative stability of star-like clusters, and planar tetracoordinate carbon structures
Peng Wang
DOI: 10.1039/D0CP06081J
Topological semimetal state with triply degenerate nodal points in a stable Cu2Te structure
Yiming Mi
DOI: 10.1039/D0CP05622G
こちらもおすすめ
(S)-四氢呋喃-3-羧酸の物理化学的性質は何ですか?
CAS番号168395-26-4の(S)-四氢呋喃-3-羧酸は、白色の結晶が特徴的な性質を持ちます。分子量は128.08であり、水に溶けやすく、アルコールなど...
塩基性硫黄化合物1,3-ジメチル-1-[5-(三氟甲基)-1,3,4-硫杂环己二酮-2-基]尿素を含む廃棄物はどのように処理すべきですか?
塩基性硫黄化合物1,3-ジメチル-1-[5-(三氟甲基)-1,3,4-硫杂环己二酮-2-基]尿素を含む廃棄物は、専門的な廃棄処理施設で焼却処理を行うべきです。ま...
インドリジン-2-カルボン酸は安全ですか?
インドリジン-2-カルボン酸は一般的に安全ですが、過度に濃い状態では刺激性があります。取り扱いには適切な防護具を使用し、直接触れや吸入を避ける必要があります。
5-甲基-2-(3-ピリジニル)-1,3-テイゾール-4-オールの市場動向や研究トレンドはどうですか?
5-甲基-2-(3-ピリジニル)-1,3-テイゾール-4-オールは、医薬品や農薬、および合成化学の分野において研究が進められています。市場動向としては、化学物質...
4,4',4''-(嘧啶-2,4,6-三基)三苯甲醛はどのように保存すればよいですか?
4,4',4''-(嘧啶-2,4,6-三基)三苯甲醛は、密閉容器に保管し、避けておくことが重要です。室温で保管し、直射日光を避けてください。
(3aR)-1,3,3-トリフェニルテトラヒドロ-3H-ピロロ[1,2-c][1,3,2]-オキザボロロールについて、適用される法規ガイドラインは何ですか?
(3aR)-1,3,3-トリフェニルテトラヒドロ-3H-ピロロ[1,2-c][1,3,2]-オキザボロロールは、GHS(国際危険物識別ルール)の分類が適用されま...
6-(4-氯苯氧基)吡啶-3-胺の代替品はありますか?
6-(4-氯苯氧基)吡啶-3-胺の代替品としては、他の芳香族アミン化合物や類似の除草剤が考えられます。ただし、他の化合物と同様に、代替品の選択には安全性と効果性...
3-フェニル-3,4-ジヒドロ-2H-1,4-ベンゾキサジンを取り扱う際の実験室安全事項は何ですか?
3-フェニル-3,4-ジヒドロ-2H-1,4-ベンゾキサジンを取り扱う際は、防塵マスク、ゴーグル、ゴム手袋を使用し、ドラフトチャンバー内で作業することを推奨しま...
掲載誌
Physical Chemistry Chemical Physics

Physical Chemistry Chemical Physics (PCCP) is an international journal co-owned by 19 physical chemistry and physics societies from around the world. This journal publishes original, cutting-edge research in physical chemistry, chemical physics and biophysical chemistry. To be suitable for publication in PCCP, articles must include significant innovation and/or insight into physical chemistry; this is the most important criterion that reviewers and Editors will judge against when evaluating submissions. The journal has a broad scope and welcomes contributions spanning experiment, theory, computation and data science. Topical coverage includes spectroscopy, dynamics, kinetics, statistical mechanics, thermodynamics, electrochemistry, catalysis, surface science, quantum mechanics, quantum computing and machine learning. Interdisciplinary research areas such as polymers and soft matter, materials, nanoscience, energy, surfaces/interfaces, and biophysical chemistry are welcomed if they demonstrate significant innovation and/or insight into physical chemistry. Joined experimental/theoretical studies are particularly appreciated when complementary and based on up-to-date approaches.



![2-Methyl-2-propanyl 1,6-diazaspiro[3.4]octane-6-carboxylate structure 2-Methyl-2-propanyl 1,6-diazaspiro[3.4]octane-6-carboxylate structure](https://static.chemtradehub.com/structs/115/1158749-79-1-81ee.webp)
![[2-(Benzyloxy)-3-bromo-5-methylphenyl]boronic acid structure [2-(Benzyloxy)-3-bromo-5-methylphenyl]boronic acid structure](https://static.chemtradehub.com/structs/870/870777-20-1-24ac.webp)