Isolation and structure of a silicocationic species with 1,3-aryl bridging between silicon atoms: a bis-silylated benzenium ion or a bridging Ph group?

文献情報

出版日 2005-11-04

DOI 10.1039/B513203G

インパクトファクター 6.222

著者

Nicholas Choi, Paul D. Lickiss, Mary McPartlin, Phindile C. Masangane, Guilaine L. Veneziani

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要旨

Hydride abstraction from (Me3Si)3CSiMePhH by Ph3C+ affords the cation [(Me3Si)2CSiMe2–Ph–SiMe2]+, which is shown by X-ray crystallography to contain the first structurally characterised example of a Ph group bridging between two silicon atoms.

掲載誌

Chemical Communications

CiteScore: 8.6

自己引用率: 4.7%

年間論文数: 2458

ChemComm publishes urgent research which is of outstanding significance and interest to experts in the field, while also appealing to the journal’s broad chemistry readership. Our communication format is ideally suited to short, urgent studies that are of such importance that they require accelerated publication. Our scope covers all topics in chemistry, and research at the interface of chemistry and other disciplines (such as materials science, nanoscience, physics, engineering and biology) where there is a significant novelty in the chemistry aspects. Major topic areas covered include: Analytical Chemistry Catalysis Chemical Biology and medicinal chemistry Computational Chemistry and Machine Learning Energy and sustainable chemistry Environmental Chemistry Green Chemistry Inorganic Chemistry Materials Chemistry Nanoscience Organic Chemistry Physical Chemistry Polymer Chemistry Supramolecular Chemistry

Isolation and structure of a silicocationic species with 1,3-aryl bridging between silicon atoms: a bis-silylated benzenium ion or a bridging Ph group?

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Chemical Communications

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