In situ determination of sulfur isotopes in sulfur-rich materials by laser ablation multiple-collector inductively coupled plasma mass spectrometry (LA-MC-ICP-MS)

文献情報

出版日 2005-12-20

DOI 10.1039/B510883G

インパクトファクター 4.023

著者

Paul R. D. Mason, Jan Košler, Paul J. Sylvester, Simon Meffan-Main

原文を見る

要旨

A new method has been developed for the accurate and precise measurement of sulfur isotopes (32S, 33S, 34S) in solids on a scale down to 80–100 μm by laser ablation multiple collector inductively coupled plasma mass spectrometry (LA-MC-ICP-MS). The method was developed independently on two different sets of instrumentation, both of which give equivalent results with comparable accuracy and precision. The first instrumental set-up utilizes Xe gas in a hexapole collision and reaction cell for interference attenuation coupled with a mass discrimination correction by external normalization using a nebulised vapour of 37Cl/35Cl standard solution. The second employs high mass resolution by sector field mass spectrometry to avoid the interfering O2+ isobars with a 30Si/29Si standard aerosol for external normalization. The external isotope mass discrimination correction was applied using the exponential law and was further calibrated for both sets of instrumentation by linear interpolation in a sample–standard bracketing method. Mean δ34SV-CDT and δ33SV-CDT show excellent agreement (within analytical error, typically 0.6 and 1.5‰, respectively) with compiled data for IAEA-S series AgS standard reference materials. Results for NIST SRM 127 (sulfate) were less accurate when calibrated against the IAEA-S series sulfides, whilst significant and consistent deviations in accuracy of up to 3‰ were observed in both sets of instrumentation for Soufre de Lacq SRM sulfur. Such generic matrix effects may be widespread in LA-ICP-MS due to differential ablation rates, particle formation, particle transport efficiency and ionization efficiency in an argon plasma.

掲載誌

Journal of Analytical Atomic Spectrometry

CiteScore: 6.2

自己引用率: 25.8%

年間論文数: 254

The Journal of Analytical Atomic Spectrometry (JAAS) is the central journal for publishing innovative research on fundamentals, instrumentation, and methods in the determination, speciation and isotopic analysis of (trace) elements within all fields of application. This includes, but is not restricted to, the most recent progress, developments and achievements in all forms of atomic and elemental detection, isotope ratio determination, molecular analysis, plasma-based analysis and X-ray techniques. The journal welcomes full papers, communications, technical notes, critical and tutorial review articles, editorials, and comments, in addition to the Atomic Spectrometry Updates (ASU) literature reviews that are prepared by an expert panel. Submissions are welcome in the following areas, but note this list reflects the current scope and authors are strongly encouraged to contact the Editorial team if they believe that their work offers potentially new and emerging research relevant to the journal remit: Fundamental studies in the following. New and existing sources for atomic emission, absorption, fluorescence and mass spectrometry and those that provide both atomic and molecular information Sample introduction techniques for solids, liquids, gases Improvements in sensitivity, selectivity, precision, accuracy and/or robustness Isotope ratio measurements, including techniques for improving precision and mass bias correction Single channel and multichannel simultaneous detection systems Chemometrics, statistics, calibration techniques and internal standardisation Theoretical and numerical modelling of fundamental processes related to all of the above methodologies Novel or improved methodologies in areas of application including, but not limited to the following. Biosciences, including elemental, speciation and isotopic analysis in biological systems, immunoassays based on metal-labeled antibodies, bio-imaging, and nanoparticle toxicology Geochemistry Environmental science Materials science, including engineered nanoparticles and quantum dots Metrology, including reference materials Forensic analysis Food and agricultural sciences Energy Archaeometry Molecular analysis. Molecular sources for elemental and isotopic analysis Atomic sources for molecular analysis Atomic and molecular techniques simultaneously used for complementary chemical information All contributions are judged on originality and quality of scientific content, and appropriateness of length to content of new science.