gem-Difluorination of 2,2-diaryl-1,3-dithiolanes by Selectfluor® and pyridinium polyhydrogen fluoride
文献情報
V. Prakash Reddy, Ramesh Alleti, Meher K. Perambuduru, Urs Welz-Biermann, Herwig Buchholz, G. K. Surya Prakash
2,2-Diaryl-1,3-dithiolanes, readily obtainable from diaryl ketones, were transformed into the corresponding gem-difluoro compounds using a novel reagent combination involving Selectfluor速 and pyridinium polyhydrogen fluoride (PPHF) under mild conditions in moderate to good yields.
関連文献
A unique heterobimetallic benzyl calciate—an organometallic mixed-metal species involving a heavy alkaline-earth metal
Marites A. Guino-o, Charles F. Campana, Karin Ruhlandt-Senge
DOI: 10.1039/B715701K
Controlled regio- and chemoselective addition of isothiocyanate to the dione moiety of a cage-opened fullerene-mixed peroxide derivative
Zheming Wang
DOI: 10.1039/B800722E
Synthesis and properties of trifluoroethoxy-coated binuclear phthalocyanine
Hideyuki Yoshiyama, Norio Shibata, Takefumi Sato, Shuichi Nakamura, Takeshi Toru
DOI: 10.1039/B800918J
Cobalt promoted copper manganese oxide catalysts for ambient temperature carbon monoxide oxidation
Christopher Jones, Stuart H. Taylor, Andrew Burrows, Mandy J. Crudace, Christopher J. Kiely, Graham J. Hutchings
DOI: 10.1039/B800052M
Pressure effects and Mössbauer spectroscopic studies on a 3D mixed-valence iron spin-crossover complex with NiAs topology
Yue-Ling Bai, Jun Tao, Rong-Bin Huang, Lan-Sun Zheng, Shao-Liang Zheng, Kazuyoshi Oshida, Yasuaki Einaga
DOI: 10.1039/B718456E
Functionalized polyesters from organocatalyzed ROP of gluOCA, the O-carboxyanhydride derived from glutamic acid
Olivier Thillaye du Boullay, Colin Bonduelle, Blanca Martin-Vaca, Didier Bourissou
DOI: 10.1039/B800852C
Phase-transfer dynamic combinatorial chemistry
Ruth Pérez-Fernández, Michael Pittelkow, Ana M. Belenguer, Jeremy K. M. Sanders
DOI: 10.1039/B718075F
Role and substrate specificity of the Streptomyces coelicolor RedH enzyme in undecylprodiginine biosynthesis
Stuart W. Haynes, Paulina K. Sydor, Anna E. Stanley, Lijiang Song, Gregory L. Challis
DOI: 10.1039/B801677A
Blue light-emitting and hole-transporting amorphous molecular materials based on diarylaminobiphenyl-functionalized bimesitylenes
Jarugu Narasimha Moorthy, Parthasarathy Venkatakrishnan, Duo-Fong Huang, Tahsin J. Chow
DOI: 10.1039/B718250C
Recent progress in the immobilization of catalysts for selective oxidation in the liquid phase
Luc Alaerts, Joos Wahlen, Pierre A. Jacobs, Dirk E. De Vos
DOI: 10.1039/B715691J
こちらもおすすめ
2-ブロモ-9,9-ジフェニル-9H-フルオレンの主な用途は何ですか?
2-溴-9,9-二苯基芴は、医薬品、工業材料、有機合成の研究分野で応用されます。特に、レーザー材料や機能性ポリマーの合成に使用されることがあります。また、蛍光色...
四氯化铱の市場動向や研究トレンドはどうですか?
四氯化铱の市場は研究開発分野で注目されており、特にナノ技術や金属有機框架(MOFs)の分野での需要が増加傾向にあります。価格は安定しており、中国や韓国での生産が...
1-(4-溴-3-氟苯基)-2-氯乙酮を含む廃棄物はどのように処理すべきですか?
1-(4-溴-3-氟苯基)-2-氯乙酮 (CAS番号: 1260857-14-4) の廃棄物は専門的な廃棄処理が必要です。まず、廃棄物は密閉された容器に収集し、...
苦参酚Kとは何ですか?
苦参酚Kは、CAS番号101236-49-1を持つ化合物で、主に天然由来の生薬から抽出されます。この化合物は、抗炎症作用や抗癌作用を持つことが報告されています。
POTASSIUM (1-(TERTBUTOXYCARBONYL)AZETIDIN-3-YL)TRIFLUOROBORATE を含む廃棄物はどのように処理すべきですか?
POTASSIUM (1-(TERTBUTOXYCARBONYL)AZETIDIN-3-YL)TRIFLUOROBORATE を含む廃棄物は、まず安全なエント...
4-庚基-4’-联苯羧酸の市場動向や研究トレンドはどうですか?
4-庚基-4’-聯苯羧酸は、特殊化学品や合成化学の分野で用いられる化学物質ですが、市場動向としては、研究開発の進展とともに需要が増加しています。また、環境配慮型...
6-ブロモ-3-メトキシ-1-フェニル-1H-インドゾールを含む廃棄物はどのように処理すべきですか?
6-ブロモ-3-メトキシ-1-フェニル-1H-インドゾールを含む廃棄物は、適切な化学廃棄処理が必要です。通常、廃棄物は密閉容器に収集され、専門の廃棄処理業者に引...
4,4-二甲基-2-吡咯烷酮はどの業界で使用されていますか?
4,4-二甲基-2-吡咯烷酮は医薬、ポリマー、センサー、半導体などの業界で広く使用されています。特に溶媒としての性能が高く評価されています。
掲載誌
Chemical Communications

ChemComm publishes urgent research which is of outstanding significance and interest to experts in the field, while also appealing to the journal’s broad chemistry readership. Our communication format is ideally suited to short, urgent studies that are of such importance that they require accelerated publication. Our scope covers all topics in chemistry, and research at the interface of chemistry and other disciplines (such as materials science, nanoscience, physics, engineering and biology) where there is a significant novelty in the chemistry aspects. Major topic areas covered include: Analytical Chemistry Catalysis Chemical Biology and medicinal chemistry Computational Chemistry and Machine Learning Energy and sustainable chemistry Environmental Chemistry Green Chemistry Inorganic Chemistry Materials Chemistry Nanoscience Organic Chemistry Physical Chemistry Polymer Chemistry Supramolecular Chemistry












![4-{2-[4-(2-Methyl-2-propanyl)phenyl]ethoxy}quinazoline structure 4-{2-[4-(2-Methyl-2-propanyl)phenyl]ethoxy}quinazoline structure](https://static.chemtradehub.com/structs/120/120928-09-8-d3db.webp)

![[4-Amino-2-(methylsulfanyl)-5-pyrimidinyl]methanol structure [4-Amino-2-(methylsulfanyl)-5-pyrimidinyl]methanol structure](https://static.chemtradehub.com/structs/588/588-36-3-fc73.webp)