Regiospecific topochemical reactions controlled by trifluoromethyl directing groups
文献情報
Jin Liu, Kelly Jo Boarman
A parallel, offset-stacked orientation was found in the crystal packing of E,E-1,4-di(o-trifluoromethyl)phenyl-1,3-butadiene. UV-irradiation of the powered crystalline sample resulted in a quantitative conversion to a single [2 + 2] cycloaddition product.
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