A study of the Rydberg states of furan (C4H4O) and deuterated furan (C4D4O) using mass-resolved (2 + 1) and (3 + 1) resonance enhanced multiphoton ionization
文献情報
Trevor Ridley, Kenneth P. Lawley, Robert J. Donovan
A combination of (i) two- and three-photon resonance enhanced multiphoton ionization techniques with linear and circular polarization, (ii) a comparison with the single-photon absorption spectrum and (iii) isotopic substitution has been used to study the Rydberg states of furan (C4H4O). The three X[2A2]c;3p states have been unambiguously assigned from the identification of the promoting modes involved in the strong false origins observed in the two-photon spectrum. The frequencies of the A1 vibrational modes of the ion-core that are Franck–Condon active are reported. The l values of the higher Rydberg states are assigned from their quantum defects and a comparison of the single-, two- and three-photon spectra, up to the ionization limit, reveals a strong propensity for excitation of d series with two photons and p and f series with one and three photons.
おすすめジャーナル

Proceedings of the National Academy of Sciences of the United States of America

European Journal of Wood and Wood Products

Journal of Medicinal Chemistry

Molecular Pharmacology

Kinetics and Catalysis

Planta Medica

Journal of Organometallic Chemistry

Helvetica Chimica Acta

Journal of Heterocyclic Chemistry

Organic Preparations and Procedures International
関連文献
The effect of flexibility on the phase diagram of simple molecular models
Carlos Vega, Carl McBride, Luis G. MacDowell
DOI: 10.1039/B107988N
Aqueous solutions at pressures up to 2 GPa: gas–gas equilibria, closed loops, high-pressure immiscibility, salt effects and related phenomena
DOI: 10.1039/B109277B
Use of ab initio interaction energies for the prediction of phase equilibria in the system nitrogen–ethane
Gabriele Raabe, Juergen Koehler
DOI: 10.1039/B108641N
Behavior of superoxide radicals formed on TiO2 powder photocatalysts studied by a chemiluminescent probe method
Yoshio Nosaka, Masatsugu Nakamura, Tsutomu Hirakawa
DOI: 10.1039/B108441K
Ionization and excitation yields in liquid water due to the primary irradiation: Relationship of radiolysis with far UV-photolysis
DOI: 10.1039/B106017C
Surface freezing in liquid Ga–Bi alloys: optical second harmonic and plasma generation study
DOI: 10.1039/B107478B
Proton relaxation and intermolecular structure of liquid formic acid: a nuclear magnetic resonance study
DOI: 10.1039/B110358J
Symmetry and distortive π-electrons in two- and three-dimensional conjugated systems
A. Rassat
DOI: 10.1039/B109712C
On the chemical properties of sedimentary sulfur in estuarine environments
G. Billon, B. Ouddane, L. Gengembre, A. Boughriet
DOI: 10.1039/B108638N
こちらもおすすめ
アエポキシアビレーターONE酢酸エステルを含む廃棄物はどのように処理すべきですか?
アエポキシアビレーターONE酢酸エステルを含む廃棄物は、焼却や専門廃棄処理が一般的です。具体的には、廃棄物は密閉容器に収集し、適切な温度と湿度の下で保存します。...
4-ヒドロキシ但線を取り扱う際の実験室安全事項は何ですか?
取り扱いには化学製品安全管理データシート(SDS)を参照してください。温度10℃以下で保存し、密閉容器に保管してください。漏れ時にはドラフトチャンバーを使用し、...
4-(3-環戊基尿素)フェノールボロネートはどの業界で使用されていますか?
4-(3-環戊基尿素)フェノールボロネートは主に医薬品産業で使用されています。この化合物は抗炎症薬や抗うつ薬の候補物質として研究されています。また、ポリマー産業...
N~1~-[3-氯-5-(三氟甲基)-2-吡啶]-1,2-乙二胺の市場動向や研究トレンドはどうですか?
市場では、安全性と効果性を基にした化学物質の需要が高まっています。研究分野では、環境に優しい代替品の開発が進んでおり、その結果、この化合物の市場需要は減少傾向に...
6-硝基苯并二氢吡喃-4-酮についての法規ガイドラインは何ですか?
6-硝基苯并二氢吡喃-4-酮(CAS番号: 68043-53-8)は、GHS(統一化された化学品の危険性的分類と標識)で急性毒性第4クラスに分類されます。EUで...
6-乙酰基-2(3H)-苯并噻唑酮は安全ですか?
安全性は化合物の使用方法によります。適切な取扱いと防護措置を講じれば、一定の安全性があります。ただし、吸入や皮膚への接触は避けてください。
3-メチル-6-(1-メチルヒドラジニル)ピリジジンはどの業界で使用されていますか?
3-メチル-6-(1-メチルヒドラジニル)ピリジジンは主に医薬品、ポリマー、センサー製造業界で使用されています。特に、医薬品産業では抗がん剤や抗真菌剤の候補物質...
tert-butyl 5-oxo-2,6-diazaspiro[3.4]octane-2-carboxylateの物理化学的性質は何ですか?
tert-butyl 5-オキソ-2,6-ジアザスパイロ[3.4]オクタネ-2-カルボキサongyangはCAS番号1330765-39-3で、分子量は334....
3-塩素メチルフェニル-4,4,5,5-テトラメチル-1,3,2-ジオキソボロラノールは安全ですか?
3-塩素メチルフェニル-4,4,5,5-テトラメチル-1,3,2-ジオキソボロラノールは、毒性が低いと考えられていますが、直接的な皮膚接触や吸入は避けるべきです...
掲載誌
Physical Chemistry Chemical Physics

Physical Chemistry Chemical Physics (PCCP) is an international journal co-owned by 19 physical chemistry and physics societies from around the world. This journal publishes original, cutting-edge research in physical chemistry, chemical physics and biophysical chemistry. To be suitable for publication in PCCP, articles must include significant innovation and/or insight into physical chemistry; this is the most important criterion that reviewers and Editors will judge against when evaluating submissions. The journal has a broad scope and welcomes contributions spanning experiment, theory, computation and data science. Topical coverage includes spectroscopy, dynamics, kinetics, statistical mechanics, thermodynamics, electrochemistry, catalysis, surface science, quantum mechanics, quantum computing and machine learning. Interdisciplinary research areas such as polymers and soft matter, materials, nanoscience, energy, surfaces/interfaces, and biophysical chemistry are welcomed if they demonstrate significant innovation and/or insight into physical chemistry. Joined experimental/theoretical studies are particularly appreciated when complementary and based on up-to-date approaches.




