From group 13–group 13 donor–acceptor bonds to triple-decker cations

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出版日 2004-10-13

DOI 10.1039/B409497M

インパクトファクター 6.222

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要旨

Donor–acceptor bonding between group 13 elements seems counter-intuitive because one normally thinks of e.g. boron and aluminium compounds as classical Lewis acids. Indeed, many such compounds have achieved industrial prominence in this regard. Recently, however, it has become possible to stabilize these and other group 13 elements in the +1 oxidation state as opposed to the archetypical +3 oxidation state. Moreover, it turns out that in the +1 oxidation state these species are excellent donors – hence the formation of these unprecedented donor–acceptor bonds. The discovery of such bonds has led, albeit indirectly, to the development of triple-decker main group cations. This aspect is also covered in the review.

掲載誌

Chemical Communications

CiteScore: 8.6

自己引用率: 4.7%

年間論文数: 2458

ChemComm publishes urgent research which is of outstanding significance and interest to experts in the field, while also appealing to the journal’s broad chemistry readership. Our communication format is ideally suited to short, urgent studies that are of such importance that they require accelerated publication. Our scope covers all topics in chemistry, and research at the interface of chemistry and other disciplines (such as materials science, nanoscience, physics, engineering and biology) where there is a significant novelty in the chemistry aspects. Major topic areas covered include: Analytical Chemistry Catalysis Chemical Biology and medicinal chemistry Computational Chemistry and Machine Learning Energy and sustainable chemistry Environmental Chemistry Green Chemistry Inorganic Chemistry Materials Chemistry Nanoscience Organic Chemistry Physical Chemistry Polymer Chemistry Supramolecular Chemistry

From group 13–group 13 donor–acceptor bonds to triple-decker cations

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