Dissociative recombination of N2OD+
文献情報
W. D. Geppert, R. Thomas, F. Hellberg, A. Ehlerding, F. Österdahl, M. af Ugglas, M. Larsson
Branching ratios and absolute cross sections have been measured for the dissociative recombination of N2OD+ using the CRYRING ion storage ring. The most dominating pathways were found to be those leading to N2 + OD (46%) and the three-body break-up producing N2 + O + D (40%). The production of N2O is not observed. The cross section of the reaction could be fitted to the expression σ = 1.25 ± 0.25 × 10−15(E/eV)−1.24±0.02, which leads to a thermal reaction rate of k(T) = 1.4 ± 0.1 × 10−6(T/300)−0.74±0.02 cm3 s−1. The findings are compared with those of the related dissociative recombination of DOCO+ as well as with earlier flowing afterglow measurements.
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