Baylis–Hillman adducts in rhodium-catalyzed 1,4-additions: unusual reactivity

文献情報

出版日 2004-04-05

DOI 10.1039/B402928C

インパクトファクター 6.222

著者

Laure Navarre, Sylvain Darses, Jean-Pierre Genet

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要旨

In the presence of a rhodium catalyst, unactivated Baylis–Hillman adducts reacted with arylboronic acids to afford trisubstituted alkenes with good yields. This highly efficient reaction (aerobic conditions, low temperature) is believed to proceeds via an unexpected mechanism involving 1,4-addition/β-hydroxy elimination steps and not π-allyl type rhodium intermediates.

掲載誌

Chemical Communications

CiteScore: 8.6

自己引用率: 4.7%

年間論文数: 2458

ChemComm publishes urgent research which is of outstanding significance and interest to experts in the field, while also appealing to the journal’s broad chemistry readership. Our communication format is ideally suited to short, urgent studies that are of such importance that they require accelerated publication. Our scope covers all topics in chemistry, and research at the interface of chemistry and other disciplines (such as materials science, nanoscience, physics, engineering and biology) where there is a significant novelty in the chemistry aspects. Major topic areas covered include: Analytical Chemistry Catalysis Chemical Biology and medicinal chemistry Computational Chemistry and Machine Learning Energy and sustainable chemistry Environmental Chemistry Green Chemistry Inorganic Chemistry Materials Chemistry Nanoscience Organic Chemistry Physical Chemistry Polymer Chemistry Supramolecular Chemistry

Baylis–Hillman adducts in rhodium-catalyzed 1,4-additions: unusual reactivity

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