Towards bulk behaviour of long hydrogenated carbon chains?

文献情報

出版日 2003-09-30

DOI 10.1039/B309100G

インパクトファクター 3.676

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要旨

The dipole forbidden A 1Δu(1Σ−u) ← X 1Σ+g transitions of the linear carbon chains HC2nH (n = 3–7) were observed in the gas phase under supersonic molecular beam conditions. The absorption position was found to form a progression to lower energy with respect to chain length. This is discussed in relation to the electronic structure of long HC2nH carbon chains (n < 14) and their trend towards bulk behaviour. It is determined that chains as long as 3 nm (e.g. HC26H) are still far from exhibiting the properties of a one-dimensional crystal.

掲載誌

Physical Chemistry Chemical Physics

CiteScore: 5.5

自己引用率: 10.3%

年間論文数: 3036

Physical Chemistry Chemical Physics (PCCP) is an international journal co-owned by 19 physical chemistry and physics societies from around the world. This journal publishes original, cutting-edge research in physical chemistry, chemical physics and biophysical chemistry. To be suitable for publication in PCCP, articles must include significant innovation and/or insight into physical chemistry; this is the most important criterion that reviewers and Editors will judge against when evaluating submissions. The journal has a broad scope and welcomes contributions spanning experiment, theory, computation and data science. Topical coverage includes spectroscopy, dynamics, kinetics, statistical mechanics, thermodynamics, electrochemistry, catalysis, surface science, quantum mechanics, quantum computing and machine learning. Interdisciplinary research areas such as polymers and soft matter, materials, nanoscience, energy, surfaces/interfaces, and biophysical chemistry are welcomed if they demonstrate significant innovation and/or insight into physical chemistry. Joined experimental/theoretical studies are particularly appreciated when complementary and based on up-to-date approaches.

Towards bulk behaviour of long hydrogenated carbon chains?

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Physical Chemistry Chemical Physics

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