Photooxidation and dark thermal oxidation of 1-butene on cationic forms of zeolite Y: a spectroscopic study
文献情報
Samantha L. Y. Tang, David J. McGarvey, Vladimir L. Zholobenko
Na, Sr, Ca, Mg and La-containing samples of zeolite Y were employed for the photooxidation of 1-butene with UV-visible light at ambient temperatures. The reactions yielded combinations of saturated and unsaturated carbonyl compounds depending on the process parameters and the type of the material utilised. Oxidation of the alkene on cationic forms of zeolite Y was also achieved in dark conditions at 30 °C. Our results demonstrated that both activity and selectivity of the oxidation were strongly affected by the cation size to charge ratio and the reaction conditions.
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Physical Chemistry Chemical Physics (PCCP) is an international journal co-owned by 19 physical chemistry and physics societies from around the world. This journal publishes original, cutting-edge research in physical chemistry, chemical physics and biophysical chemistry. To be suitable for publication in PCCP, articles must include significant innovation and/or insight into physical chemistry; this is the most important criterion that reviewers and Editors will judge against when evaluating submissions. The journal has a broad scope and welcomes contributions spanning experiment, theory, computation and data science. Topical coverage includes spectroscopy, dynamics, kinetics, statistical mechanics, thermodynamics, electrochemistry, catalysis, surface science, quantum mechanics, quantum computing and machine learning. Interdisciplinary research areas such as polymers and soft matter, materials, nanoscience, energy, surfaces/interfaces, and biophysical chemistry are welcomed if they demonstrate significant innovation and/or insight into physical chemistry. Joined experimental/theoretical studies are particularly appreciated when complementary and based on up-to-date approaches.

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