High tetraalkylaluminate fluxionality in half-sandwich complexes of the trivalent rare-earth metals

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出版日 2003-03-24

DOI 10.1039/B212754G

インパクトファクター 6.222

著者

Reiner Anwander, Michael G. Klimpel, H. Martin Dietrich, Dmitry J. Shorokhov, Wolfgang Scherer

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要旨

Steric factors govern the formation of half-sandwich complexes (C5Me4R)Ln[N(SiHMe2)2]2 according to acid–base reactions utilising Ln[N(SiHMe2)2]3(thf)2 and substituted cyclopentadienes. Subsequent trimethylaluminium-promoted silylamide elimination produces the first half-sandwich bis(tetramethylaluminate) complexes (C5Me4R)Ln(AlMe4)2.

掲載誌

Chemical Communications

CiteScore: 8.6

自己引用率: 4.7%

年間論文数: 2458

ChemComm publishes urgent research which is of outstanding significance and interest to experts in the field, while also appealing to the journal’s broad chemistry readership. Our communication format is ideally suited to short, urgent studies that are of such importance that they require accelerated publication. Our scope covers all topics in chemistry, and research at the interface of chemistry and other disciplines (such as materials science, nanoscience, physics, engineering and biology) where there is a significant novelty in the chemistry aspects. Major topic areas covered include: Analytical Chemistry Catalysis Chemical Biology and medicinal chemistry Computational Chemistry and Machine Learning Energy and sustainable chemistry Environmental Chemistry Green Chemistry Inorganic Chemistry Materials Chemistry Nanoscience Organic Chemistry Physical Chemistry Polymer Chemistry Supramolecular Chemistry

High tetraalkylaluminate fluxionality in half-sandwich complexes of the trivalent rare-earth metals

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