Synthesis, absolute configuration and conformation of optically active 1,2-homoheptafulvalene

文献情報

出版日 2003-01-15

DOI 10.1039/B210949M

インパクトファクター 3.876

著者

Shunji Ito, Mitsuhiro Kurita, Sigeru Kikuchi, Toyonobu Asao, Yoshitora Ito, Masaji Oda, Hideo Sotokawa, Akio Tajiri, Noboru Morita

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要旨

An optically active 1,2-homoheptafulvalene was successfully synthesized and subjected to spectroscopic investigation. The cycloaddition of the optically active hydrocarbon with tetracyanoethylene (TCNE) and 4-phenyl-1,2,4-triazoline-3,5-dione (PTAD) gave a [4 + 2] cycloadduct and a mixture of [8 + 2] cycloadducts, respectively, which are both optically active.

掲載誌

Organic & Biomolecular Chemistry

CiteScore: 3.4

自己引用率: 10.3%

年間論文数: 1041

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