Adsorption-induced dimensional changes of solids

文献情報

出版日 2002-10-16

DOI 10.1039/B206883D

インパクトファクター 3.676

著者

Tim S. Jakubov, David E. Mainwaring

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要旨

A new approach based on the thermodynamic theory of vacancy solutions and Hooke's law is developed for the description of the elastic strain of isotropic solid adsorbents during physical adsorption. The equation linking a relative strain with the equilibrium parameters of adsorption is derived. The explicit expression allowing calculation of the contribution from solid strain to heat of adsorption is obtained. Validity of the developed method has been confirmed by comparing the theoretically predicted dimensional changes on adsorption to the experimentally studied system zeolite CaA–krypton where both contraction and expansion occurred.

掲載誌

Physical Chemistry Chemical Physics

CiteScore: 5.5

自己引用率: 10.3%

年間論文数: 3036

Physical Chemistry Chemical Physics (PCCP) is an international journal co-owned by 19 physical chemistry and physics societies from around the world. This journal publishes original, cutting-edge research in physical chemistry, chemical physics and biophysical chemistry. To be suitable for publication in PCCP, articles must include significant innovation and/or insight into physical chemistry; this is the most important criterion that reviewers and Editors will judge against when evaluating submissions. The journal has a broad scope and welcomes contributions spanning experiment, theory, computation and data science. Topical coverage includes spectroscopy, dynamics, kinetics, statistical mechanics, thermodynamics, electrochemistry, catalysis, surface science, quantum mechanics, quantum computing and machine learning. Interdisciplinary research areas such as polymers and soft matter, materials, nanoscience, energy, surfaces/interfaces, and biophysical chemistry are welcomed if they demonstrate significant innovation and/or insight into physical chemistry. Joined experimental/theoretical studies are particularly appreciated when complementary and based on up-to-date approaches.

Adsorption-induced dimensional changes of solids

文献情報

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Physical Chemistry Chemical Physics

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