Critical dilution
文献情報
The critical dilution can be derived in a natural fashion from gel point theory. Theoretically, the existence of the critical dilution, γc, appears almost obvious. In contrast, experimentally, there has been much confusion as to whether the critical dilution occurs or not. To resolve this question, we re-examine the gelation theory developed in our laboratory in light of the Matejka–Dusek experiments, the result giving a confirmation of the soundness of the concept of critical dilution.
関連文献
Preparation of highly accessible mordenite coatings on ceramic monoliths at loadings exceeding 50% by weight
M. A. Ulla, E. Miro, R. Mallada, J. Coronas, J. Santamaría
DOI: 10.1039/B315386J
Peroxides in ordered nanoporous silicas: clean alternatives to transition metal oxidants for the removal of toxic gases
Michael J. Hudson, Dominic B. Jackson, Jessica L. Ward, Matt J. Chinn
DOI: 10.1039/B310872D
VIII(OH){O2C–C6H4–CO2}.(HO2C–C6H4–CO2H)x(DMF)y(H2O)z (or MIL-68), a new vanadocarboxylate with a large pore hybrid topology : reticular synthesis with infinite inorganic building blocks?
K. Barthelet, J. Marrot, G. Férey, D. Riou
DOI: 10.1039/B312589K
Zinc metalloporphyrin-functionalised nanoparticle anion sensors
Paul D. Beer, David P. Cormode, Jason J. Davis
DOI: 10.1039/B313658B
Significant and differential acceleration of dephosphorylation of the insecticides, paraoxon and parathion, caused by alkali metal ethoxides
Ik-Hwan Um, Sang-Eun Jeon, Mi-Hwa Baek, Hye-Ran Park
DOI: 10.1039/B310055C
Thioglycosynthases: double mutant glycosidases that serve as scaffolds for thioglycoside synthesis
Jennifer Marles, R. Antony J. Warren
DOI: 10.1039/B313155F
A novel azulene synthesis from the Ramirez ylide involving two different modes of its reaction with activated alkynes
Lee J. Higham, P. Gabriel Kelly, David M. Corr, Helge Müller-Bunz, Brian J. Walker, Declan G. Gilheany
DOI: 10.1039/B316759C
Synthesis of new thermotropic liquid crystalline polyurethanes containing biphenyl mesogens using a novel AB-type self-polycondensation
T. Ranganathan, C. Ramesh, Anil Kumar
DOI: 10.1039/B312826A
Nickel-catalyzed highly chemoselective cocyclotrimerization of arynes with allenes: a novel method for 10-methylene-9,10-dihydrophenanthrenes
Jen-Chieh Hsieh, Dinesh Kumar Rayabarapu, Chien-Hong Cheng
DOI: 10.1039/B315795D
Pore size effects in the pyrolysis of 1,3-diphenylpropane confined in mesoporous silicas
Michelle K. Kidder, Phillip F. Britt, Zongtao Zhang, Sheng Dai, A. C. Buchanan, III
DOI: 10.1039/B310405B
こちらもおすすめ
噻奈普汀乙酯の物理化学的性質は何ですか?
CAS番号66981-77-9の噻奈普汀乙酯は、結晶性白色粉末であり、分子量は476.9 g/molです。この化合物は水に溶けにくく、一般的には有機溶媒で溶解し...
アミピシリン不純物Fとは何ですか?
アミピシリン不純物Fは、CAS番号124774-48-7の化合物です。これは、抗生物質アミピシリンの生産過程で生成される不純物の一つであり、(4S)-2-({[...
イリジウム(I)ヘキサフルオロフォスファートの代替品はありますか?
イリジウム(I)ヘキサフルオロフォスファートの代替品として、他の有機金属化合物や非有機金属化合物が使用されることがあります。具体的には、ダイゾニウム塩や他の金属...
含有3-(苯氧基甲基)苯硼酸频那醇酯の廃棄物はどのように処理すべきですか?
含有3-(苯氧基甲基)苯硼酸频那醇酯の廃棄物は、安全な方法で処理する必要があります。まず、廃棄物を適切な容器に収集し、避けて保管します。次に、専門の廃棄処理業者...
2-甲基辛-1-醇を取り扱う際の実験室安全事項は何ですか?
取り扱う際は、密閉のゴーグルと手袋を着用することが推奨されます。ドラフトチャンバーを使用し、漏洩時には速やかに取り扱いを中止し、適切な排気設備を使用してください...
3α-アセトキノイドコレステロールエステルはどのように保存すればよいですか?
3α-アセトキノイドコレステロールエステルは、常温から低温(0-5℃)の暗所で保存し、密閉容器に入れることで安定性を保つことが推奨されます。また、湿気や酸素から...
2-ぶンジロキシ-4-(トリフルオロメチル)フェノルビノン酸の主な用途は何ですか?
2-ぶンジロキシ-4-(トリフルオロメチル)フェノルビノン酸は、化学合成の触媒としての使用や、医薬品の合成材料としての役割があります。また、特定の合成路線で使用...
(2S,3R)-2-氨基-3-甲基丁二酸はどのように合成されますか?
(2S,3R)-2-氨基-3-甲基丁二酸は、2-ヒドロキシ-3-メチル丁酸とアミノ化反応を行うことで合成されます。触媒としてジクロロメタンが使用され、選択性と収...
1-Benzyl-2-phenyl-1H-imidazoleはどのように保存すればよいですか?
この化合物は常温で避けてください。直射日光を避け、密閉容器で保存し、湿気を防水の容器に入れて保管してください。
掲載誌
Physical Chemistry Chemical Physics

Physical Chemistry Chemical Physics (PCCP) is an international journal co-owned by 19 physical chemistry and physics societies from around the world. This journal publishes original, cutting-edge research in physical chemistry, chemical physics and biophysical chemistry. To be suitable for publication in PCCP, articles must include significant innovation and/or insight into physical chemistry; this is the most important criterion that reviewers and Editors will judge against when evaluating submissions. The journal has a broad scope and welcomes contributions spanning experiment, theory, computation and data science. Topical coverage includes spectroscopy, dynamics, kinetics, statistical mechanics, thermodynamics, electrochemistry, catalysis, surface science, quantum mechanics, quantum computing and machine learning. Interdisciplinary research areas such as polymers and soft matter, materials, nanoscience, energy, surfaces/interfaces, and biophysical chemistry are welcomed if they demonstrate significant innovation and/or insight into physical chemistry. Joined experimental/theoretical studies are particularly appreciated when complementary and based on up-to-date approaches.










![4-Nitrophenyl N-{[(2-methyl-2-propanyl)oxy]carbonyl}-L-isoleucinate structure 4-Nitrophenyl N-{[(2-methyl-2-propanyl)oxy]carbonyl}-L-isoleucinate structure](https://static.chemtradehub.com/structs/169/16948-38-2-c88f.webp)
methanone structure [4-(Hydroxymethyl)phenyl](phenyl)methanone structure](https://static.chemtradehub.com/structs/814/81449-01-6-786d.webp)
![[3-Chloro-5-(diethylcarbamoyl)phenyl]boronic acid structure [3-Chloro-5-(diethylcarbamoyl)phenyl]boronic acid structure](https://static.chemtradehub.com/structs/957/957120-59-1-febc.webp)

