On product state distributions in triatomic unimolecular reactions Part III. Barrier processes with a path defined by bent geometries

文献情報

出版日 2002-04-04

DOI 10.1039/B110235B

インパクトファクター 3.676

著者

P. Larregaray, L. Bonnet, J. C. Rayez

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要旨

We develop an analytical theory of state distributions in the products of three-atom unimolecular reactions involving a barrier and a dissociation path defined by bent geometries. The approach combines transition state theory (TST), kinematic rotations (KR) and the linear transformation model (LTM), published recently. Its predictions are compared with quasiclassical trajectory calculations on a model potential energy surface.

掲載誌

Physical Chemistry Chemical Physics

CiteScore: 5.5

自己引用率: 10.3%

年間論文数: 3036

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