Neutron reflectivity studies of the free liquid surface of methylcyclohexane–perfluoromethylcyclohexane near the critical endpoint
文献情報
The surface structure of the liquid mixture methylcyclohexane (MCH)–perfluoromethylcyclohexane (PFMCH) has been investigated by specular neutron reflectometry from 42 K below to 10 K above the upper critical solution temperature TUCS=46.13°C. The results have been interpreted in the light of the Abele′s layer model which indicates that the reflectivity throughout the experimental temperature range is satisfactorily represented by a model with two relatively thin layers interposed between the vapour phase and a well-characterised subphase. The twin-layer region is everywhere richer in PFMCH, the component of lower surface tension, than the immediate subphase and is thus regarded as an adsorbed layer. For TUCS
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