Specific chemical bond relaxation unraveled by analysis of shake-up satellites in the oxygen single site double core hole spectrum of CO2
文献情報
Anthony Ferté, Francis Penent, Jérôme Palaudoux, Hiroshi Iwayama, Eiji Shigemasa, Yasumasa Hikosaka, Kouichi Soejima, Pascal Lablanquie, Richard Taïeb, Stéphane Carniato
We recently developed [A. Ferté, et al., J. Phys. Chem. Lett., 2020, 11, 4359] a method to compute single site double core hole (ssDCH or K−2) spectra. We refer to that method as NOTA+CIPSI. In the present paper this method is applied to the O K−2 spectrum of the CO2 molecule, and we use this as an example to discuss in detail its convergence properties. Using this approach, theoretical spectra in excellent agreement with the experimental one are obtained. Thanks to a thorough interpretation of the shake-up states responsible for the main satellite peaks and through comparison with the O K−2 spectrum of CO, we can highlight the clear signature of the two non-equivalent carbon oxygen bonds in the oxygen ssDCH CO2 dication.
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